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2-DIETHYLAMINOVINYL DERIVATIVES OF HALOGENATED 1,4-QUINONES: SYNTHETIC AND STRUCTURAL ASPECTS

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Abstract

Diethylaminovinyl derivatives of halogenated 1,4-quinones (enaminoquinones) are produced by the interaction of halogenated 1,4-quinones with N,N-diethyl-N-vinylamine obtained in situ from Et2NH and MeCHO. Molecular and crystal structures of enaminoquinones halogenated in the quinone fragment are determined. It is shown that in the solid phase, atoms of the entire push-pull system of enaminoquinones lie practically in one plane.

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Funding

The study was supported by the Russian Science Foundation (project No. 17-73-10238).

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Authors and Affiliations

  1. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. I. Zhivetyeva, I. A. Zayakin, I. Yu. Bagryanskaya & E. V. Tretyakov

  2. Novosibirsk State University, Novosibirsk, Russia

    I. Yu. Bagryanskaya & E. V. Tretyakov

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  1. S. I. Zhivetyeva
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  2. I. A. Zayakin
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  3. I. Yu. Bagryanskaya
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  4. E. V. Tretyakov
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Correspondence to S. I. Zhivetyeva.

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Zhivetyeva, S.I., Zayakin, I.A., Bagryanskaya, I.Y. et al. 2-DIETHYLAMINOVINYL DERIVATIVES OF HALOGENATED 1,4-QUINONES: SYNTHETIC AND STRUCTURAL ASPECTS. J Struct Chem 61, 1253–1259 (2020). https://doi.org/10.1134/S0022476620080107

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  • DOI: https://doi.org/10.1134/S0022476620080107

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