Skip to main content
SpringerLink
Log in

Structure of Complexes of Thiophosphorylthiourea Compounds with a Silver(I) Cation and Triphenylphosphine

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Molecular and crystal structures of three monovalent silver complexes with chelate thiophosphorylthiourea ligands and triphenylphosphine are determined in the context of studying complexing properties of N-thiophosphorylated thioureas, thioamides, and thiosemicarbazides with the general formula RC(S)NHP(S)(Oi-Pr)2 (R = AlkNH, Alk2N, ArNH, PyNH, Ph, PhNHNH, NH2(Et)N) towards copper (I) and silver (I) cations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. A. Safin, M. G. Babashkina, M. Bolte, and Y. Garcia. CrystEngComm, 2012, 14, 774.

    Article  CAS  Google Scholar 

  2. D. A. Safin, M. G. Babashkina, M. Bolte, T. Pape, F. E. Hahn, M. L. Verizhnikov, A. R. Bashirov, and A. Klein. Dalton Trans., 2010, 39, 11577.

    Article  CAS  Google Scholar 

  3. F. D. Sokolov, M. G. Babashkina, F. Fayon, A. I. Rakhmatullin, D. A. Safin, T. Pape, and F. E. Hahn. J. Organomet. Chem., 2009, 694, 167.

    Article  CAS  Google Scholar 

  4. F. D. Sokolov, M. G. Babashkina, D. A. Safin, A. I. Rakhmatullin, F. Fayon, N. G. Zabirov, M. Bolte, V. V. Brusko, J. Galezowska, and H. Kozlowski. Dalton Trans., 2007, 4693.

  5. M. G. Babashkina, D. A. Safin, L. Szyrwiel, M. Kubiak, F. D. Sokolov, Y. V. Starikov, and H. Kozlowski. Z. Anorg. Allg. Chem., 2009, 635, 554.

    Article  CAS  Google Scholar 

  6. D. A. Safin, M. G. Babashkina, M. Bolte, and A. Klein. CrystEngComm, 2011, 13, 568.

    Article  CAS  Google Scholar 

  7. D. A. Safin, M. G. Babashkina, M. Bolte, and A. Klein. Inorg. Chim. Acta, 2010, 363, 1897.

    Article  CAS  Google Scholar 

  8. D. A. Safin, M. G. Babashkina, M. Bolte, and F. E. Hahn. Dalton Trans., 2011, 40, 4806.

    Article  CAS  Google Scholar 

  9. C. R. Groom, I. J. Bruno, M. P. Lightfoot, and S. C. Ward. Acta Crystallogr., Sect. B, 2016, 72, 171.

    Article  CAS  Google Scholar 

  10. E. R. Shakirova. Complexes of N-Thiophosphorylated Thioureas, Thioamides and Thiosemicarbazides with Copper(I) and Silver(I) Cations. Cand. Sci. (Chem.) Dissertation. Kazan State University: Kazan, 2010.

    Google Scholar 

  11. G. M. Sheldrick. SADABS. Madison, WI, USA: Bruker AXS, 1997.

    Google Scholar 

  12. G. M. Sheldrick. Acta Crystallogr., Sect. A, 2015, 71, 3–8.

    Article  CAS  Google Scholar 

  13. G. M. Sheldrick. Acta Crystallogr., Sect. C, 2015, 71, 3–8.

    Article  CAS  Google Scholar 

  14. L. J. Farrugia. J. Appl. Crystallogr., 2012, 45, 849.

    Article  CAS  Google Scholar 

  15. APEX2. (Version 2.1). SAINTPlus. Data Reduction and Correction Program (Version 7.31A). Bruker AXS: Madison, WI, USA, 2006.

  16. A. L. Spek. Acta Crystallogr., Sect. D., 2009, 56, 148.

    Article  CAS  Google Scholar 

  17. I. A. Litvinov and F. A. Karamov. J. Struct. Chem., 2019, 3(11), 1812.

    Article  Google Scholar 

Download references

Acknowledgments

The authors thank E. R. Shakirova and F. D. Sokolov for providing crystals for the X-ray experiments.

Funding

Molecular and crystal structures were studied by I.A. Litvinov within the State Contract for the FRC Kazan Scientific Center RAS, the obtained results were discussed in the Kazan National Research Technical University-KAI.

Author information

Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Republic of Tatarstan, Kazan, Russia

    I. A. Litvinov & O. A. Lodochnikova

  2. Kazan Tupolev National Research Technical University, Republic of Tatarstan, Kazan, Russia

    F. A. Karamov

Authors
  1. I. A. Litvinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. A. Lodochnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. A. Karamov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Litvinov.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Additional Information

The single crystals of investigated compounds were studied in the Collective Federal Center for Spectral Analysis of the A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center RAS on the basis of Laboratory of Diffraction Research Methods.

Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 6, pp. 975–979.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Litvinov, I.A., Lodochnikova, O.A. & Karamov, F.A. Structure of Complexes of Thiophosphorylthiourea Compounds with a Silver(I) Cation and Triphenylphosphine. J Struct Chem 61, 923–927 (2020). https://doi.org/10.1134/S0022476620060128

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476620060128

Keywords

Search

Navigation