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Two New Entangled Zn and Cd Coordination Polymers Based on a Rich “Mix” Feature of the O- and N-Donor Ligand System: Synthesis, Structure, and Fluorescent Properties

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Abstract

A prominent mixed-ligand system with rich “mix” features, which are rigid multicarboxylate O-donor ligands cooperating with flexible bisazole N-donor linkers, is explored to coordinate with Zn2+/Cd2+ centers. Two new entangled coordination polymers ([Cd(Hbtc)(bbi)] (1) and [Zn(btec)0.5(dtp)]·5H2O (2)) are gained. Complex 1 exhibits a fascinating 3D (3,5)-connected net with a Schläfli symbol of the (63.610) topology, and 3D nets penetrate into each other to give rise to twofold interpenetrations. Complex 2 displays a 2D layer with similar 9.9×12.0 Å2 hexagonal channels, the adjacent layers stacking with each other to form a 3D supramolecular structure. The effects and functions of the ligands in the complexes are discussed. Moreover, the thermal stabilities and fluorescence properties of complexes 1 and 2 are investigated.

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Funding

This work was supported by Science and Technology Project of Panzhihua, P. R. China (20180816, 2018CY-G-13).

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Authors and Affiliations

  1. State Key Laboratory of Titanium and Vanadium Testing, Panzhihua University, Panzhihua, P. R. China

    X. F. Wang

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  1. X. F. Wang
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Correspondence to X. F. Wang.

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Additional Information

CCDC 1910151–1910152 contains the supplementary crystallographic data for this work. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving. html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or email: deposit@ccdc.cam.ac.uk).

Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 6, pp. 966–974.

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Wang, X.F. Two New Entangled Zn and Cd Coordination Polymers Based on a Rich “Mix” Feature of the O- and N-Donor Ligand System: Synthesis, Structure, and Fluorescent Properties. J Struct Chem 61, 914–922 (2020). https://doi.org/10.1134/S0022476620060116

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  • DOI: https://doi.org/10.1134/S0022476620060116

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