Abstract
A new copper(II) complex with bis(4,4′-(ethane-1,2-diylbis(azanediyl))bis(3-(2-(4-fluorophenyl) hydrazinyl)pentan-2-one) (1) is synthesized and analyzed by single crystal X-ray diffraction. The crystals are monoclinic: a = 11.1340(9) Å, b = 11.6716(10) Å, c = 18.7797(16) Å, β = 94.792(2)°, V = 2431.9(4) Å3, space group P21/n, Z = 4, ρcalc = 1.713 mg/m3, R = 0.0695. The environment of the copper atom is formed by four donor nitrogen atoms (N1, N3, N4, N6). These atoms are at the equatorial position. The N6 atom slightly deviates from the middle plane. Phenyl rings are not involved in the coordination. Additional crystallographic data are available from the Cambridge Crystallography Data Center under number CCDC 1907359.
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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 6, pp. 952–958.
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Bakhmanova, F.N., Mamedova, F.O., Mamedova, G.Z. et al. Crystallographic Analysis of a Copper(II) Complex with bis(4,4′-Ethane-1,2-Diylbis(Azanediyl))-bis(3-(2-(4-Flurophenyl)Hydrazinyl)Pentan-2-One). J Struct Chem 61, 899–905 (2020). https://doi.org/10.1134/S0022476620060098
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DOI: https://doi.org/10.1134/S0022476620060098