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Coordination of a (Npy)2NimineNamine-Donor Oxazolidine Ligand Toward CdX2 (X = Cl, Br, I) with 1:1 and 2:1 M:L Molar Ratios Along with Spectral, Theoretical, and Structural Studies

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Abstract

A series of reactions between an oxazolidine ligand 2-(2-(pyridin-2-yl)oxazolidin-3-yl)-N-(pyridin-2-ylmethylene)ethanamine (POPME) and CdX2 (X = Cl, Br, I) salts with different M:L molar ratios (1:1 and 2:1) is experimentally studied to determine the most stable product of these reactions. All products are characterized by the elemental analysis, FTIR, Raman, and 1H NMR spectroscopy, and single crystal X-ray diffraction. Examinations reveal that only one product is formed from 1:1 and 2:1 M:L reactions between each cadmium(II) halide with POPME. The thermodynamic stability and charge distribution patterns of the compound containing bromide are analyzed by DFT and NBO.

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  1. Inorganic Chemistry Department, Faculty of Chemistry, Urmia University, Urmia, Iran

    Z. Mardani

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  1. Z. Mardani
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Additional Information

CCDC 939155 for 2mono contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB21EZ, UK; fax: +44(0)1223-336033; email: deposit@ccdc.cam.ac.uk). Structure factor table is available from the authors.

Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 6, pp. 904–912.

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Mardani, Z. Coordination of a (Npy)2NimineNamine-Donor Oxazolidine Ligand Toward CdX2 (X = Cl, Br, I) with 1:1 and 2:1 M:L Molar Ratios Along with Spectral, Theoretical, and Structural Studies. J Struct Chem 61, 852–860 (2020). https://doi.org/10.1134/S0022476620060037

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