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Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene

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Abstract

By the interaction of Nb(NMe2)5 and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF4) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe2)(μ-F)2(μ-NMe2) NbF2(NMe2)] (1) is obtained. The reaction of Nb(NMe2)5 and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF4) tetrafluoroborate yields [(IMes)2H][NbF6] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.

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References

  1. A. J. Arduengo, R. L. Harlow, and M. Kline. J. Am. Chem. Soc, 1991, 113, 361–363.

    Article  CAS  Google Scholar 

  2. N-Heterocyclic Carbenes. From Laboratory Curiosities to Efficient Synthetic Tools / Ed. S. Diez-Gonzalez. 2nd ed. RS. Publishing, 2017.

  3. D. M. Flanigan, F. Romanov-Michailidis, N. A. White, and T. Rovis. Chem. Rev., 2015, 115, 9307–9387.

    Article  CAS  Google Scholar 

  4. Y. Wang and G. H. Robinson. Inorg. Chem., 2011, 50, 12326–12337.

    Article  CAS  Google Scholar 

  5. C. D. Martin, M. Soleilhavoup, and G. Bertrand. Chem. Sci., 2013, 4, 3020–3030.

    Article  CAS  Google Scholar 

  6. V. Nesterov, D. Reiter, P. Bag, P. Frisch, R. Holzner, A. Porzelt, and S. Inoue. Chem. Rev., 2018, 118, 9678–9842.

    Article  CAS  Google Scholar 

  7. M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, and S. Zacchini. Chem. Commun., 2014, 50, 4472–4474.

    Article  CAS  Google Scholar 

  8. M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, and S. Zacchini. Dalton Trans., 2016, 45, 6939–6948.

    Article  CAS  Google Scholar 

  9. Z.-H. Wei, W. Zhang, G. Luo, F. Xu, Y.-X. Mei, and H. Cai. New J. Chem., 2016, 40, 6270–6275.

    Article  CAS  Google Scholar 

  10. M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, C. Pinzino, and S. Zacchini. Inorg. Chem., 2016, 55, 4173–4182.

    Article  CAS  Google Scholar 

  11. M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, and S. Zacchini. J. Coord. Chem., 2016, 69, 2766–2774.

    Article  CAS  Google Scholar 

  12. P. A. Petrov, T. S. Sukhikh, and M. N. Sokolov. Dalton Trans., 2017, 46, 4902–4906.

    Article  CAS  Google Scholar 

  13. X. Bantreil and S. P. Nolan. Nat. Protoc., 2010, 6, 69–77.

    Article  Google Scholar 

  14. G. R. Fulmer, A. J. M. Miller, N. H. Sherden, H. E. Gottlieb, A. Nudelman, B. M. Stoltz, J. E. Bercaw, and K. I. Goldberg. Organometallics, 2010, 29, 2176–2179.

    Article  CAS  Google Scholar 

  15. G. M. Sheldrick, Acta Crystallogr. A, 2015, 71, 3–8.

    Article  Google Scholar 

  16. G. M. Sheldrick, Acta Crystallogr. C, 2015, 71, 3–8.

    Article  Google Scholar 

  17. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann. J. Appl. Crystallogr., 2009, 42, 339–341.

    Article  CAS  Google Scholar 

  18. J. L. Durham, W. B. Wilson, D. N. Huh, R. McDonald, and L. F. Szczepura. Chem. Commun., 2015, 51, 10536–10538.

    Article  CAS  Google Scholar 

  19. F. A. Cotton, M. P. Diebold, and W. J. Roth. Inorg. Chem., 1988, 27, 3596–3600.

    Article  CAS  Google Scholar 

  20. T. Saito, H. Nishiyama, K. Kawakita, M. Nechayev, B. Kriegel, H. Tsurugi, and J. Arnold, K. Mashima. Inorg. Chem., 2015, 54, 6004–6009.

    Article  CAS  Google Scholar 

  21. F. A. Cotton and W. J. Roth. Inorg. Chem., 1984, 23, 945–947.

    Article  CAS  Google Scholar 

  22. F. A. Cotton, S. A. Duraj and W. J. Roth. Inorg. Chem., 1984, 23, 3592–3596.

    Article  CAS  Google Scholar 

  23. J. T. Scheper, K. C. Jayaratne, L. M. Liable-Sands, G. P. A. Yap, A. L. Rheingold, and C. H. Winter. Inorg. Chem., 1999, 38, 4354–4360.

    Article  CAS  Google Scholar 

  24. A. V. Virovets, M. N. Sokolov, and D. Fenske. J. Strust. Chem., 2001, 42(5), 864–867.

    Article  Google Scholar 

  25. A. L. Guschin, M. N. Sokolov, E. V. Peresypkina, and V. P. Fedin. J. Strust. Chem., 2008, 49(4), 753–757.

    Article  Google Scholar 

  26. M. N. Sokolov, A. V. Rogachev, and A. V. Virovets. J. Strust. Chem., 2013, 54(2), 451–453.

    Article  Google Scholar 

  27. M. L. Cole and P. C. Junk. CrystEngComm, 2004, 6, 173–176.

    Article  CAS  Google Scholar 

  28. A. J. Arduengo, S. F. Gamper, M. Tamm, J. C. Calabrese, F. Davidson, and H. A. Craig. J. Am. Chem. Soc, 1995, 117, 572–573.

    Article  CAS  Google Scholar 

  29. C. Jones, D. P. Mills, and R. P. Rose. J. Organomet. Chem., 2006, 691, 3060–3064.

    Article  CAS  Google Scholar 

  30. M. A. Schmidt, P. Müller, and M. Movassaghi. Tetrahedron. Lett., 2008, 49, 4316–4318.

    Article  CAS  Google Scholar 

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Acknowledgments

The authors are grateful to Prof. V.A. Nadolinny (Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences) for studying EPR spectra.

Funding

The work was supported by RFBR project 18-03-00269.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Petrov, E. A. Golubitskaya, N. B. Kompankov, T. S. Sukhikh & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    P. A. Petrov, E. A. Golubitskaya, I. V. Eltsov, T. S. Sukhikh & M. N. Sokolov

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  1. P. A. Petrov
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  2. E. A. Golubitskaya
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  3. N. B. Kompankov
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  4. I. V. Eltsov
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  5. T. S. Sukhikh
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  6. M. N. Sokolov
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Corresponding author

Correspondence to P. A. Petrov.

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The authors declare that they have no conflict of interests.

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 12, pp. 2075-2081.

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Petrov, P.A., Golubitskaya, E.A., Kompankov, N.B. et al. Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene. J Struct Chem 60, 1989–1994 (2019). https://doi.org/10.1134/S0022476619120151

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  • DOI: https://doi.org/10.1134/S0022476619120151

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