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Metal-Organic Coordination Polymers Based on the Anions of Perfluorinated Dicarboxylic Acids

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Abstract

Two new coordination polymers are obtained: layered [Hdabco][Sc2(H20)2(OH)(tFBDC)3]-3/2C4HgO2 (1) (dabco=1,4-diazabicyclo[2.2.2]octane) and chain-like [Zn(CH3OH)4(oFBPDC)]-2CH3OH (2). They are formed by anions of perfluorinated terephthalic (tFBDC2) and biphenyl-4,4'-dicarboxylic (oFBPDC2) acids. The composition and structure of the obtained compounds are determined by the single crystal X-ray diffraction analysis.

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Funding

The work was supported by RFBR project 17-03-00027.

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Correspondence to V. P. Fedin.

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The authors declare that they have no conflict of interests.

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 12, pp. 2050-2056.

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Cheplakova, A.M., Samsonenko, D.G. & Fedin, V.P. Metal-Organic Coordination Polymers Based on the Anions of Perfluorinated Dicarboxylic Acids. J Struct Chem 60, 1965–1970 (2019). https://doi.org/10.1134/S0022476619120126

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  • DOI: https://doi.org/10.1134/S0022476619120126

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