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Methoxy-Substituted Transition Metal β-Diketonates: Synthesis and Properties

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Abstract

Novel volatile complexes of Ni(II), Co(II), Mn(II), Zn(II) with methoxy-substituted β-diketonate ligands L = (CH3)2C(OCH3)-CO-CH-CO-C(CH3)3 and LF = (CH3)2C(OCH3)-CO-CH-CO-CF3 are obtained. The novel compounds are identified by a complex of techniques, including CHF elemental, mass spectrometric, and NMR spectroscopic analyses. According to the X-ray crystallographic analysis data, in the crystals, NiL2 and ZnL2 are asymmetric binuclear complexes in which metal atoms have a different coordination environment composed of ligand oxygen atoms (c.n.= 6 and 5) and are bridged by oxygen atoms, both chelate and from one of the methoxy groups. The mixed-ligand complex [NiL(dpm)]2 (dpm = dipivaloylmethanate: 2,2,6,6-tetramethyl-3,5-heptandionate) has a similar binuclear structure. It is found that complexes with non-fluorinated ligands pass to the gas phase as monomers whereas fluorine-containing complexes pass as dimers. The compounds are paramagnetic, except zinc complexes. In the binuclear complexes based on non-fluorinated ligands, a ferromagnetic exchange interaction of magnetic moments is observed while for fluorine-containing ligands it is antiferromagnetic.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. Urkasym kyzy, V. V. Krisyuk, A. E. Turgambaeva, I. A. Baidina, V. Yu. Komarov, E. V. Korotaev & I. V. Korolkov

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  1. S. Urkasym kyzy
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  2. V. V. Krisyuk
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  3. A. E. Turgambaeva
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  4. I. A. Baidina
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  5. V. Yu. Komarov
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  6. E. V. Korotaev
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  7. I. V. Korolkov
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Correspondence to S. Urkasym kyzy.

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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 10, pp. 1701–1713.

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Urkasym kyzy, S., Krisyuk, V.V., Turgambaeva, A.E. et al. Methoxy-Substituted Transition Metal β-Diketonates: Synthesis and Properties. J Struct Chem 60, 1635–1647 (2019). https://doi.org/10.1134/S0022476619100093

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  • DOI: https://doi.org/10.1134/S0022476619100093

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