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Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt

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Abstract

From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc= 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.

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Funding

The work was supported by RFBR (project No. 18-73-00054).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    D. B. Vasilchenko, P. A. Topchiyan, S. V. Tkachev, I. A. Baidina, I. V. Korolkov, E. Yu. Filatov & D. G. Sheven

  2. Novosibirsk State University, Novosibirsk, Russia

    D. B. Vasilchenko, P. A. Topchiyan & E. Yu. Filatov

Authors
  1. D. B. Vasilchenko
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  2. P. A. Topchiyan
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  3. S. V. Tkachev
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  4. I. A. Baidina
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  5. I. V. Korolkov
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  6. E. Yu. Filatov
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  7. D. G. Sheven
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Correspondence to D. B. Vasilchenko.

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The authors declare that they have no conflict of interests.

Supplementary materials for this paper are available for authorized users at doi 10.1134/S0022476619080122.

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 8, pp. 1379–1386.

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Vasilchenko, D.B., Topchiyan, P.A., Tkachev, S.V. et al. Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt. J Struct Chem 60, 1327–1334 (2019). https://doi.org/10.1134/S0022476619080122

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  • DOI: https://doi.org/10.1134/S0022476619080122

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