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Synthesis, X-Ray Crystal Structure, and Catalytic Epoxidation Property of an Oxovanadium(V) Complex with Hydrazone and Ethyl Maltol Ligands

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Abstract

A new oxovanadium(V) complex [VO(BH)(EM)], where BH = N′-(2-hydroxybenzylidene)-4-trifluoromethylbenzohydrazide, EM = ethyl maltol, is synthesized and fully characterized based on the elemental analysis, FT-IR, UV-Vis, and 1H NMR spectra. The complex is also characterized by single crystal X-ray diffraction, which indicates that the V atom adopts the octahedral coordination. The hydrazone ligand behaves as a tridentate ligand, and the ethyl maltol ligand behaves as a bidentate ligand. The catalytic epoxidation property of the complex is investigated.

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Funding

This work was supported by the Collaborative Innovation Plan of Hubei Province for Key Technology of Eco-Ramie Industry.

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Authors and Affiliations

  1. Engineering Research Center for Clean Production of Textile Printing and Dyeing, Ministry of Education, Wuhan Textile University, Wuhan, P. R. China

    Y. M. Cui & P. Zhang

  2. School of Environmental Engineering, Wuhan Textile University, Wuhan, P. R. China

    Y. M. Cui, Y. Q. Wang, X. X. Su & H. Huang

Authors
  1. Y. M. Cui
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  2. Y. Q. Wang
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  3. X. X. Su
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  4. H. Huang
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  5. P. Zhang
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Corresponding author

Correspondence to P. Zhang.

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Conflict of Interests

The authors declare that they have no conflict of interests.

Additional Information

CCDC number 1824512 contains the supplementary crystallographic data for the complex. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Center, 12, Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336 033; or e-mail: deposit@ccdc.cam.ac.uk.

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 8, pp. 1351–1357.

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Cui, Y.M., Wang, Y.Q., Su, X.X. et al. Synthesis, X-Ray Crystal Structure, and Catalytic Epoxidation Property of an Oxovanadium(V) Complex with Hydrazone and Ethyl Maltol Ligands. J Struct Chem 60, 1299–1305 (2019). https://doi.org/10.1134/S0022476619080092

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  • DOI: https://doi.org/10.1134/S0022476619080092

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