Skip to main content
SpringerLink
Log in

Elaboration, Vibrational Study and Thermal Behavior of Lacunar Apatites NaPb3−xCdxCa(PO4)3 (0 ≤ x ≤ 1)

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

In this work we are interested in the synthesis of a new solid solution type NaPb3–xCdxCa(PO4)3; (0 ≤ x ≤ 1). The lacunar apatite series are synthesized by a solid-state reaction and studied by X-ray diffraction, infrared and Raman scattering spectroscopy, thermal gravimetric analysis, and differential scanning calorimetry. The crystal structure of these compounds was refined using the Rietveld method. These compounds crystallize in the hexagonal system (space group P63/m) with a number of units per crystal lattice Z = 2. The structure is formed by [PO4]3− tetrahedra and Pb2+/Ca2+/Cd2+ ions, which constitute the basic skeleton of the structure. The Pb2+/Ca2+/Cd2+ ions occupy the 6h sites, whereas the 4f sites are occupied in half by the Pb2+/Ca2+/Cd2+ ions and the other half by the Na+ ions. The observed frequencies in the Raman and infrared spectra are explained and discussed based on the factor group analysis and by comparison with similar apatites. The vibrational spectroscopy results are in good agreement with the X-ray diffraction measurements. The internal modes of (PO4)3− tetrahedra are assigned and corroborate well with the factor group analysis for the symmetry P63/m. We also investigated the thermal stability of these apatite materials by differential scanning calorimetry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. C. Elliott. Structure and Chemistry of the Apatites and Other Calcium Orthophosphates. Elsevier: Amsterdam, 1994, 18, 137.

    Google Scholar 

  2. D. McConnell. Apatites, Applied Mineralogy, vol. 5. Springer: New York/Vienna, 1963.

  3. G. Wright, and G. Montel. C.R. Acad Sci. Paris, 1969, 268C, 2077.

    Google Scholar 

  4. R. Z. LeGeros, M. H. Taheri, G. B. Quirolgico, and J. P. Legeros. In: Proceedings of the Second International Conference on Phosphorus Compounds. Boston, 1980, April, 89.

    Google Scholar 

  5. M. El Koumiri, S. Oishi, S. Sato, L. El Ammari, and B. Elouadi. Mater. Res. Bull., 2000, 35, 503–513.

    Article  CAS  Google Scholar 

  6. N. Leroy and E. Bres. Eur. Cells Mater., 2001, 2, 36.

    Article  CAS  Google Scholar 

  7. St. Naray-Szabo. Z Kristallogr., 1930, 75, 387.

    CAS  Google Scholar 

  8. K. Sudarsanan and R. A. Youner. Ada Crystallogr. B, 1969, 25(8), 1534.

    Article  CAS  Google Scholar 

  9. L. Merker and H. Wondratschek. Z. Kristallogr., 1957, 109, 110.

    Article  CAS  Google Scholar 

  10. G. Engel. J. Solid State Chem., 1973, 6, 293.

    Article  CAS  Google Scholar 

  11. M. Quarton, M. T. Oumba, W. Freundlich, and A. W.Kolsi. Mater. Res. Bull., 1984, 19, 1063–1068.

    Article  CAS  Google Scholar 

  12. R. Ternane, M. Férid, N. Kbir-Ariguib, and M. Trabelsi-Ayedi. J. Alloys Compd, 2000, 308, 83.

    Article  CAS  Google Scholar 

  13. M. Azrour, L. El Ammari, Y. Le Fur, and B. Elouadi. J. Solid State Chem., 1998, 141, 373–377.

    Article  CAS  Google Scholar 

  14. M. Mathew, W. E. Brown, M. Austin, and T. Negas. J. Solid State Chem., 1980, 35, 69–76.

    Article  CAS  Google Scholar 

  15. M. Azdouz, B. Manoun, M. Azrour, L. Bih, L. El Ammari, S. Benmokhtar, and P. Lazor. J. Mol. Struct., 2010, 963, 258–266.

    Article  CAS  Google Scholar 

  16. B. Manoun, M. Azdouz, M. Azrour, R. Essehli, S. Benmokhtar, L. El Ammari, A. Ezzahi, A. Ider, and P. Lazor. J. Mol. Struct., 2011, 986, 1–9.

    Article  CAS  Google Scholar 

  17. S. Lahrich, B. Manoun, and M. A. El Mhammedi. Talanta, 2016, 149, 158–167.

    Article  CAS  PubMed  Google Scholar 

  18. S. Lahrich, B. Manoun, and M. A. El Mhammedi. S. Afr. J. Chem. Engineering, 2017, 23, 98–106.

    Google Scholar 

  19. M. Azrour, M. Azdouz, B. Manoun, R. Essehli, S. Benmokhtar, L. Bih, L. E l Ammari, A. Ezzahi, A. Ider, and A. Ait Hou. J. Phys. Chem. SoL, 2011, 72, 1199–1205.

    Article  CAS  Google Scholar 

  20. S. Lahrich, B. Manoun, and M. A. El Mhammedi. Mater. Res. Bull., 2014, 59, 349–357.

    Article  CAS  Google Scholar 

  21. S. Lahrich, B. Manoun, and M. A. El Mhammedi. Mater. Chem. Phys., 2017, 188, 75–85.

    Article  CAS  Google Scholar 

  22. M. Abudoureheman, S. Han, X. Dong, B.-H. Lei, Y. Wang, Z. Yang, X. Long, and S. Pan. J. Alloys Comp., 2017, 690, 330–336.

    Article  CAS  Google Scholar 

  23. S. Louihi, M. Azdouz, Z. Chchiyai, B. Manoun, Y. Tamraoui, A. Nia, E. Magna, J. Biya, and P. Lazor. J. Appl. Surfaces and Interfaces, 2018, 3, 28–35.

    Google Scholar 

  24. R. Ternane, M. Ferid, N. Kbir-Ariguib, and M. Trabelsi-Ayedi. J. Alloys Compd, 2000, 308, 83–86.

    Article  CAS  Google Scholar 

  25. J. Rodriguez-Carvajal. Collected Abstractsof Powder Diffraction Meeting. Toulouse, France, 1990, 127–128.

    Google Scholar 

  26. T. Roisnel and J. Rodriguez-Carvajal. Mater. Sci. Forum, 2001, 118, 378–381.

    Google Scholar 

  27. A. Boultif and D. Louër. J. Appl. Crystattogr., 1991, 24, 987–993.

    Article  CAS  Google Scholar 

  28. H. M. Rietveld. J. Appl. Crystattogr., 1969, 2, 65–71.

    Article  CAS  Google Scholar 

  29. M. Ben Baaziz, M. Azdouz, M. Azrour, A. Batan, and B. Manoun. J. Ghent Res., 2018, 42, 564–571.

    Google Scholar 

  30. G. Caglioti, A. Paoletti, and F. P. Ricci. Nucl Inst rum., 1958, 3, 223.

    Article  CAS  Google Scholar 

  31. G. Engel, W. Götz, and R. Eger. Z. Anorg. Allg. Chem., 1979, 449, 127–134.

    Article  CAS  Google Scholar 

  32. W. G. Fateley, F. R. Dollish, N. T. McDevitt, and F. F. Bentley. Infrared and Raman Selection Rules for Molecular and Lattice Vibrations: The Correlation Method. Wiley-Interscience: New York, 1972, 162–164.

    Google Scholar 

  33. M. Toumi, L. Smiri, and A. Bulou. J. Solid State Chem., 2000, 149, 308–313.

    Article  CAS  Google Scholar 

  34. S. Lahrich, B. Manoun, and M. A. El Mhammedi. Mater. Res. Bull, 2014, 59, 349–357.

    Article  CAS  Google Scholar 

  35. J. Carpena and J.-L. Lacout. L’actualité Chimique, 2005, 66–71.

    Google Scholar 

  36. J. Carpena and J.-L. Lacout. L’actualité Chimique, 1997, 2, 3–9.

    Google Scholar 

  37. C. A. Kan and G. A. L. Meijer. Animal Feed Sci. Technol, 2007, 133, 84–108.

    Article  CAS  Google Scholar 

  38. A. S. Chardi and J. Nadal. Chemosphere, 2007, 68, 703–711.

    Article  CAS  Google Scholar 

  39. Amany H. Abd El Hameed, E. Eweda Wedad, A. A. Abou-Taleb Khadiga, and H. I. Mira. Ann. Agric. Sci., 2015, 60(2), 345–351.

    Article  Google Scholar 

  40. A. Bahdod, S. El Asri, A. Saoiabi, T. Coradin, and A. Laghzizil. Water Res., 2009, 43, 313–318.

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Physical Chemistry of Materials, Department of Chemistry, Faculty of Science and Techniques, Errachidia, University Moulay Ismaïl, Meknes, Morocco

    M. Ben Baaziz, M. Azdouz & M. Azrour

  2. Laboratory of Materials Science, Medium and Modelling (LS3M), University Hassan 1st FPK, Khouribga, Morocco

    B. Manoun

  3. Laboratory of Spectrometry, Materials and Archaeomaterials, Department of Physics, Faculty of Sciences, Zitoune, University Moulay Ismaïl, Meknes, Morocco

    M. El Amraoui

Authors
  1. M. Ben Baaziz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Azdouz
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Azrour
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. B. Manoun
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. El Amraoui
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Azrour.

Additional information

Conflict of Interests

The authors declare that they have no conflict of interests.

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 8, pp. 1338–1350.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baaziz, M.B., Azdouz, M., Azrour, M. et al. Elaboration, Vibrational Study and Thermal Behavior of Lacunar Apatites NaPb3−xCdxCa(PO4)3 (0 ≤ x ≤ 1). J Struct Chem 60, 1285–1298 (2019). https://doi.org/10.1134/S0022476619080080

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476619080080

Keywords

Search

Navigation