Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of a New Binuclear Copper(II) Carboxylate Complex as a Precursor for Copper(II) Oxide Nanoparticles

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

A paddle-wheel copper(II) carboxylate complex of the type [Cu2(2-nb)4(EtOH)2] (1), where 2-nb = 2-nitrobenzoate, is synthesized and characterized by single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The results show that the complex has a square pyramidal geometry around the metal center. Combustion of copper(II) carboxylate gives copper(II) oxide nanoparticles which were characterized by powder XRD, SEM, EDX, and IR analyses. This study indicates that the coordination compound represents a suitable single precursor for the synthesis of CuO nanoparticles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. R. de Campos, M. A. Ribeiro, W. X. C. Oliveira, D. O. Reis, H. O. Stumpf, A. C. Doriguetto, F. C. Machado, C. B. Pinheiro, F. Lloret, M. Julve, J. Cano, and M. V. Marinho. Dalton Trans., 2016, 45, 172–189.

    Article  CAS  PubMed  Google Scholar 

  2. S. S. Batool, S. R. Gilani, M. N. Tahir, and W. T. A. Harrison. J. Struct. Chem., 2016, 57, 991–996.

    Article  CAS  Google Scholar 

  3. G. J. Brewer. J. Am. Coll. Nutr., 2009, 28, 238–242.

    Article  PubMed  Google Scholar 

  4. K. Balamurugan and W. Schaffner. BBA Mol. Cell. Res., 2006, 1763, 737–746.

    CAS  Google Scholar 

  5. A. Golobič, L. Ožbolt, F. Pohleven, I. Leban, and P. Šegedin. Acta. Chim. Slov., 2006, 53, 238–244.

    Google Scholar 

  6. R. Vafazadeh, Z. Moghadas, and A. C. Willis. J. Coord. Chem., 2015, 68, 4255–4271.

    Article  CAS  Google Scholar 

  7. N. Shahabadi, S. M. Fili, and M. Shahlaei. J. Coord. Chem., 2015, 68, 3667–3684.

    Article  CAS  Google Scholar 

  8. J. O. Noyce, H. Michels, and C. W. Keevil. Appl. Environ. Microbiol., 2007, 73, 2748–2750.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  9. G. Borkow and J. Gabbary. FASEB J., 2004, 18, 1728–1730.

    Article  CAS  PubMed  Google Scholar 

  10. Z. J. Chen, C. N. Xu, J. L. Zhu, D. D. Yang, S. S. Zhao, Y. N. Chen, and S. S. Qian. Acta Chem. Slov., 2016, 63, 165–172.

    Article  CAS  Google Scholar 

  11. Y. Wang, X. Zhang, Q. Zhang, and Z. Yang. BioMetals., 2016, 23, 265–273.

    Article  CAS  Google Scholar 

  12. X. Wang, J. Yang, L. Shi, and M. Gao. Nano. Res. Lett., 2016, 11, 125–132.

    Article  CAS  Google Scholar 

  13. Y. Z. Feng and X. L. Zheng. Nanoscale. Lett., 2010, 10, 4762–4766.

    Article  CAS  Google Scholar 

  14. S. Ko, J. I. Lee, H. S. Yang, S. Park, and U. Jeong. Adv. Mater., 2012, 24, 4451–4456.

    Article  CAS  PubMed  Google Scholar 

  15. M. Y. Zhu and G. W. Diao. Catal. Sci. Technol., 2012, 2, 82–84.

    Article  CAS  Google Scholar 

  16. L. B. Luo, X. H. Wang, C. Xie, Z.J. Li, R. Lu, X.B. Yang, and J. Lu. Nanoscale Res. Lett., 2014, 9, 637–644.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  17. R. V. Kumar, Y. Diamant, and A. Gedanken. Chem. Mater., 2000, 12, 2301–2305.

    Article  CAS  Google Scholar 

  18. A. A. Eliseev, A. V. Lukashin, A. A. Vertegel, L. I. Heifetsand, and A. I. Zhirov. Mater. Res. Innovations, 2000, 3, 308–312.

    Article  CAS  Google Scholar 

  19. K. Borgohain, J. B. Singh, M. V. R. Rao, T. Shripathiand, and S. Mahamuni. Phys. Rev. B, 2000, 61, 11093–11096.

    Article  CAS  Google Scholar 

  20. M. Salavati-Niasari and F. Davar. Mater. Lett., 2009, 63, 441–443.

    Article  CAS  Google Scholar 

  21. G. M. Sheldrick. Acta Cryst., 2015, A71, 3–8.

    Google Scholar 

  22. G. M. Sheldrick. Acta Cryst., 2008, A64, 112–122.

    Article  CAS  Google Scholar 

  23. W. Hwang, H. Qian, S. Gou, and C. Yao. J. Mol. Struct., 2005, 743, 183–190.

    Article  CAS  Google Scholar 

  24. A. M. Qadir. Orient. J. Chem., 2017, 33, 968–970.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Physics, Bharathidasan University, Tiruchirappalli, India

    K. Karthik

  2. Department of Chemistry, College of Science, Salahaddin University, Erbil, Kurdistan Region, Iraq

    A. M. Qadir

Authors
  1. K. Karthik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. M. Qadir
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Qadir.

Additional information

Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1172-1178.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Karthik, K., Qadir, A.M. Synthesis and Crystal Structure of a New Binuclear Copper(II) Carboxylate Complex as a Precursor for Copper(II) Oxide Nanoparticles. J Struct Chem 60, 1126–1132 (2019). https://doi.org/10.1134/S002247661907014X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002247661907014X

Keywords

Search

Navigation