Skip to main content
SpringerLink
Log in

Synthesis, Crystal Structure, and Photoluminescence of a Lithium Perchlorate Complex with 18-Crown-6

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The reaction of lithium perchlorate salt and 18-crown-6 (18C-6) in the commercial tetrahydrofuran (THF) solvent leads to a novel important intermediate Li(18C-6)(H2O)2(ClO4)⋅0.5((18C-6)⋅THF) (1). The crystal structure shows it as a mononuclear lithium complex, and the asymmetric unit contains a Li(H2O)2(18C-6) moiety, one half of the 18C-6 guest molecule, one half of the disordered THF solvent molecule, and a perchlorate anion. Solid-state photoluminescence experiments show that complex 1 emits violet luminescence, and its possible emission mechanism is investigated in detail based on theoretical calculations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. J. Pedersen. J. Am. Chem. Soc., 1967, 89, 2495–2496.

    Article  CAS  Google Scholar 

  2. C. J. Pedersen. J. Am. Chem. Soc., 1967, 89, 7017–7036.

    Article  CAS  Google Scholar 

  3. J. J. Christensen, J. O. Hill, and R. M. Izatt. Science, 1971, 174, 459–467.

    Article  CAS  PubMed  Google Scholar 

  4. R. D. Hancock. J. Chem. Educ., 1992, 69, 615–621.

    Article  CAS  Google Scholar 

  5. D. J. Cram. Angew. Chem. Int. Ed. Engl., 1986, 25, 1039–1057.

    Article  Google Scholar 

  6. J. W. Steed. Coord. Chem. Rev., 2001, 215, 171–221.

    Article  CAS  Google Scholar 

  7. U. Olsher, R. M. Izatt, J. S. Bradshaw, and N. K. Dalley. Chem. Rev., 1991, 91, 137–164.

    Article  CAS  Google Scholar 

  8. Y. Kikuchi and Y. Sakamoto. Anal. Chim. Acta, 2000, 403, 325–332.

    Article  CAS  Google Scholar 

  9. P. Groth. Acta Chem. Scand. A, 1982, 36, 109–115.

    Article  Google Scholar 

  10. T.-L. Chang, M. Zhao, N.-H. Hu, and Z.-S. Jin. Rev. Chim. Miner., 1987, 24, 382–390.

    CAS  Google Scholar 

  11. N. K. Dalley, J. D. Lamb, and A. Y. Nazarenko. Supramol. Chem., 1997, 8, 345–350.

    Article  CAS  Google Scholar 

  12. T. Steiner. Angew. Chem. Int. Ed., 2002, 41, 48–76.

    Article  CAS  Google Scholar 

  13. C. R. Groom, I. J. Bruno, M. P. Lightfoot, and S. C. Ward. Acta Crystallogr., 2016, B72, 171–179.

    CAS  Google Scholar 

  14. X. Liu and K.-L. Huang. Inorg. Chem., 2009, 48, 8653–8655.

    Article  CAS  PubMed  Google Scholar 

  15. X. Liu, K.-L. Huang, G.-M. Liang, M.-S. Wang, and G.-C. Guo. CrystEngComm, 2009, 11, 1615–1620.

    Article  CAS  Google Scholar 

  16. X. Liu, L. Li, Y.-Z. Yang, and K.-L. Huang. Dalton Trans., 2014, 43, 4086–4092.

    Article  CAS  PubMed  Google Scholar 

  17. L. Li, C.-H. Wang, X.-L. Zhang, and X. Liu. Eur. J. Inorg. Chem., 2015, 859–863.

    Google Scholar 

  18. X. Liu, W.-J. Ru, and Z. Zhao. Z. Naturforsch., 2017, 72b, 167–170.

    Article  CAS  Google Scholar 

  19. X. Liu, Z. Zhao, C.-H. Wang, S. Fu, and K.-L. Huang. RSC Adv., 2017, 7, 40632–40639.

    Article  CAS  Google Scholar 

  20. Rigaku, CrystalClear Version 1.35, Rigaku Corporation, 2002.

  21. Siemens, SHELXTLTM Version 5 Reference Manual. Siemens Energy & Automation Inc., Madison, Wisconsin, U.S.A., 1994.

  22. M. Segall, P. Linda, M. Probert, C. Pickard, P. Hasnip, S. Clark, and M. Payne. Materials Studio CASTEP, version 2.2, Accelrys, San Diego, CA, 2002.

    Google Scholar 

  23. M. Segall, P. Linda, M. Probert, C. Pickard, P. Hasnip, S. Clark, and M. J. Payne. J. Phys: Condens. Matter., 2002, 14, 2717–2743.

    CAS  Google Scholar 

  24. D. R. Hamann, M. Schluter, and C. Chiang. Phys. Rev. Lett., 1979, 43, 1494–1497.

    Article  CAS  Google Scholar 

Download references

Funding

We gratefully acknowledge the financial support of the National Natural Science Foundation of China (21071156), the Natural Science Foundation of Chongqing (CSTC2015JCYJA50007), and the Project of International Science and Technology Cooperation Base Construction in Chongqing (CSTC2014GJHZ20002).

Author information

Authors and Affiliations

  1. Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing, P. R. China

    Y. -F. Jian, B. Fu, S. Fu & X. Liu

Authors
  1. Y. -F. Jian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Fu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Fu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. X. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to X. Liu.

Additional information

Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1165-1171.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jian, Y.F., Fu, B., Fu, S. et al. Synthesis, Crystal Structure, and Photoluminescence of a Lithium Perchlorate Complex with 18-Crown-6. J Struct Chem 60, 1119–1125 (2019). https://doi.org/10.1134/S0022476619070138

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476619070138

Keywords

Search

Navigation