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Crystal Structure of Cationic η3-Methallylpalladium Complexes Bearing Aliphatic Iminopyridine Ligands

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Abstract

Three aliphatic ligands are synthesized and fully characterized by IR, 1H and 13C NMR spectroscopy. These ligands react with a zerovalent compound Pd(dba)2 in the presence of methallyloxytris(dimethylamino) phosphonium hexafluorophosphate salt [C4H7OP(NMe2)3]+\({\rm{PF}}_6^-\) as an allylating agent for the synthesis of cationic η3-methallylpalladium complexes to give three cationic mononuclear η33-methallylpalladium complexes in high yields. These formed complexes are characterized by IR, 1H NMR and 13C NMR spectroscopy. One of them is characterized by X-ray diffraction. A DFT-optimized structure is also discussed.

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  1. Laboratoire de Chimie Hétérocyclique, Produits Naturels et Réactivité : L.C.H.P.N.R, Faculté des Sciences de Monastir, Bd de l’Environnement, Monastir, Tunisia

    S. Dridi, A. Mechria & M. Msaddek

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Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1157-1164.

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Dridi, S., Mechria, A. & Msaddek, M. Crystal Structure of Cationic η3-Methallylpalladium Complexes Bearing Aliphatic Iminopyridine Ligands. J Struct Chem 60, 1110–1118 (2019). https://doi.org/10.1134/S0022476619070126

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