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Structure and Magnetic Properties of Lanthanide Compounds with the 3,6-Di(Tert-Butyl)-1,2-Benzoquinone Radical Anion

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Abstract

Molecular and crystal structures of mononuclear lanthanide (Ln) compounds with the 3,6-di(tert-butyl)-1,2-benzoquinone (SQ) radical anion of the composition [Ln(SQ)3(THF)2] (Ln = Pr, Nd, Eu, Tb, Dy), [Ln(SQ)3(Q)], (Ln = Gd, Eu; Q – 3,6-di(tert-butyl)-1,2-benzoquinone), [La(SQ)3(Q)(THF)], [CeIV(SQ)4], [NaLn(SQ)4(THF)3]·0.25C6H14 (Ln = Gd, Tb), [NaLn(SQ)4(Q)(THF)] (Ln = La, Pr) are determined. The study of the magnetic properties of isolated heterospin solid phases reveals that intramolecular antiferromagnetic exchange interactions between unpaired electrons of SQ moieties dominate in them. At T≤2 K [Dy(SQ)3(THF)2] exhibits the properties typical of a metamagnetic compound.

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Funding

The structural and magnetic measurements in this research was supported by 17-13-01022 and FASO (synthesis of compounds).

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    G. V. Romanenko, S. V. Fokin, G. A. Letyagin, A. S. Bogomyakov & V. I. Ovcharenko

  2. Novosibirsk State University, Novosibirsk, Russia

    G. A. Letyagin

Authors
  1. G. V. Romanenko
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  2. S. V. Fokin
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  3. G. A. Letyagin
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  4. A. S. Bogomyakov
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  5. V. I. Ovcharenko
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Corresponding author

Correspondence to G. V. Romanenko.

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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1139-1148.

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Romanenko, G.V., Fokin, S.V., Letyagin, G.A. et al. Structure and Magnetic Properties of Lanthanide Compounds with the 3,6-Di(Tert-Butyl)-1,2-Benzoquinone Radical Anion. J Struct Chem 60, 1091–1100 (2019). https://doi.org/10.1134/S0022476619070102

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  • DOI: https://doi.org/10.1134/S0022476619070102

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