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Crystal Structure of Na2[OsCl6]

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Abstract

Salt Na2[OsCl6] is obtained by the interaction of H2[OsCl6]·H2O with NaCl in boiling concentrated hydrochloric acid. According to the single crystal X-ray diffraction data, the substance crystallizes in the cubic system, space group Fmm, a = 9.7461(11) Å, V= 925.8(3) Å3, Z = 4, R1= 0.029, wR2 = 0.070. The compound is characterized by UV-vis and IR spectroscopy.

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References

  1. N. M. Sinitsyn, A. M. Kunaev, E. I. Ponomareva, N. M. Bondar, V. N. Pichkov, Z. S. Abisheva, and V. P. Zaitsev. Metallurgy of Osmium [in Russian]. Nauka: Alma-Ata, 1981.

    Google Scholar 

  2. S. A. Cotton. Chemistry of Precious Metals. Blackie Academic&Professional: London, 1997.

    Book  Google Scholar 

  3. Gmelin Handbuch der Anorganischen Chemie. System No 66. Osmium. Springer: Berlin, 1980.

  4. A. I. Efimov, L. P. Belorukova, I. V. Vasilkova, and V. P. Chechev. Properties of Inorganic Compounds. Handbook [in Russian]. Khimiya: Leningrad, 1983.

    Google Scholar 

  5. G. Brauer. Handbook of Preparative Inorganic Chemistry. Academic Press: New York, 1965, 5.

  6. Internet Source: https://www.strem.com

  7. S. I. Ginzburg, N. A. Ezerskaya, I. V. Prokofieva, N. V. Fedorenko, V. I. Shlenskaya, and N. K. Bel’skii. Analytical Chemistry of Platinum Metals [in Russian]. Nauka: Moscow, 1972.

    Google Scholar 

  8. T. G. G. Battye, L. Kontogiannis, O. Johnson, H. R. Powell, and A. G. W. Leslie. Acta Crystallogr., 2011, D67, 271.

    Google Scholar 

  9. P. R. Evans. Acta Crystallogr., 2005, D62, 72.

    Google Scholar 

  10. G. M. Sheldrick. Acta Crystallogr, 2015, C71, 3.

    Google Scholar 

  11. K. Ch. Jorgensen, Mol. Phys., 1959, 2, 309.

    Article  CAS  Google Scholar 

  12. O. V. Rudnitskaya, E. K. Kultyshkina, E. V. Dobrokhotova, and I. V. Anan’ev. Russ. J. Coordinat. Chem., 2014, 40(12), 911.

    Article  CAS  Google Scholar 

  13. O. V. Rudnitskaya, E. K. Kultyshkina, E. V. Dobrokhotova, V. S. Podvoyskaya, V. N. Khrustalev, P. V. Dorovatovskii, V. A. Lazarenko, and Y. V. Zubavichus. Polyhedron, 2017, 134, 114.

    Article  CAS  Google Scholar 

  14. H. Takazawa, S. Ohba, and Y. Saito. Acta Crystallogr., 1990, B46, 166.

    Article  CAS  Google Scholar 

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Funding

The publication was prepared with the support of Program 5-100 of the People’s Friendship University of Russia.

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Correspondence to O. V. Rudnitskaya.

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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1134-1138.

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Rudnitskaya, O.V., Kultyshkina, E.K., Dobrokhotova, E.V. et al. Crystal Structure of Na2[OsCl6]. J Struct Chem 60, 1086–1090 (2019). https://doi.org/10.1134/S0022476619070096

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  • DOI: https://doi.org/10.1134/S0022476619070096

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