Abstract
A reaction of RhCl3·3H2O with P(CH2OH)3 (THP) and H2S in methanol results in the formation of a new trinuclear complex [Rh3(μ3-S)2(μ2-S)(μ2-Cl)2(THP)6]Cl (1) with a yield of 29%. The structure of 1 is determined by X-ray crystallography. With the same initial compounds with hexamethyldisilthiane as a sulfide source a binuclear [Rh2(μ2-S2)(μ2-S)(THP)6]2+ complex is obtained in which mono- and disulfide bridges are present simultaneously. The latter is isolated and structurally characterized as [Rh2(μ-S2)(μ2-S)(THP)6][Mo6Cl14]·0.6MeOH (2) with a yield of 12%. The compounds obtained are characterized by mass spectrometry and 31P NMR spectra.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
N. Pinault, and D. W. Bruce. Coord. Chem. Rev., 2003, 241, 1.
W. A. Herrmann and C. W. Kohlpaintne. Angew. Chem., Int. Ed. Engl., 1993, 32, 1524.
K. K. Kothar, K. Raghuraman, N. K. Pillarsetty et al. Appl. Radiat. Isot., 2003, 58, 543.
J. R. Dilworth and S. J. Parrot. Chem. Soc. Rev., 1998, 27, 43.
P. J. Blower. Trans. Met. Chem., 1998, 23, 109.
J. W. Ellis, K. N. Harrison, P. A. T. Hoye et al. Inorg. Chem., 1992, 31, 3026.
K. Raghuraman, N. Pillarsetty, W. A. Volkert et al. J. Am. Chem. Soc., 2002, 124, 7276.
D. E. Berning, K. V. Katti, L. G. Barbour et al. Inorg. Chem., 1998, 37, 334.
B. Driessen-Hölscher and J. Heinen. J. Organomet. Chem., 1998, 570, 141.
A. Fukuoka, W. Kosugi, F. Morishita et al. Chem. Commun., 1999, 489.
M. N. Sokolov, A. V. Anyushin, R. Hernandez-Molina et al. Pure Appl. Chem., 2017, 89, 379.
A. G. Algarra, M. G. Basallote, M. J. Fernández-Trujillo et al. Inorg. Chem., 2007, 46, 7668.
M. G. Basallote, M. J. Fernández-Trujillo, J. Á. Pino-Chamorro et al. Inorg. Chem., 2012, 51, 6794.
T. F. Beltrán, R. Llusar, M. N. Sokolov et al. Inorg. Chem., 2013, 52, 8713.
M. N. Sokolov, A. V. Anyushin, A. V. Virovets et al. Inorg. Chem. Comm., 2011, 14, 1659.
A. V. Anyushin, M. N. Sokolov, A. V. Virovets et al. Inorg. Chem. Comm., 2012, 24. 225.
A. V. Anyushin, M. N. Sokolov, A. V. Virovets et al. J. Struct. Chem., 2013, 54, 638.
A. V. Anyushin, P. A. Abramov, N. B. Kompankov et al. Russ. J. Coord. Chem., 2013, 39, 77.
A. V. Anyushin, E. V. Korotaev, A. Yu. Andreeva et al. Russ. Chem. Bull., Int. Ed., 2016, 173.
H. J. Xu, Y. Lu, M. E. Farmer et al. J. Am. Chem. Soc., 2017, 139, 2200.
X. Wu, X. Li, A. Zanotti-Gerosa et al. Chem. Eur. J., 2008, 14, 2209.
T. K. Hyster and T. Rovis. Chem. Commun., 2011, 47, 11846.
M. N. Sokolov and P. A. Abramov. Coord. Chem. Rev., 2012, 256, 1972.
F. Cecconi, C. A. Ghilardi, S. Midollini et al. Inorg. Chim. Acta, 1989, 155, 5.
P. Nannelli, B. P. Block, D. A. Edwards et al. Inorg. Synth., 1970, 12, 170.
V. P. Fedin, O. A. Gerasko, and V. E. Fedorov. Izv. SB AS SSSR. Ser. Khim., 1988, 19, 64.
G. M. Sheldrick. SADABS. University of Göttingen, Germany, 1996.
G. M. Sheldrick. Acta Cryst., 2015, C71, 3.
C. B. Hübschle, G. M. Sheldrick, and B. Dittrich. J. Appl. Cryst., 2011, 44, 1281.
C. Schmidt and W. S. Sheldrick. Z. Kristallogr. - New Cryst. Struct., 1998, 213, 265.
H.-M. Wu, Y-H. Chang, Y.-F. Tsai et al. Dalton Trans., 2015, 44, 4468.
T. Suzuki, K. Isobe, K. Kashiwabara et al. J. Chem. Soc. Dalton Trans., 1996, 3779.
Funding
The work was supported by RFBR (grant 17-03-00663).
Author information
Authors and Affiliations
Corresponding author
Additional information
Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1120-1127.
Rights and permissions
About this article
Cite this article
Anyushin, A.V., Kompan’kov, N.B., Abramov, P.A. et al. Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)3. J Struct Chem 60, 1072–1079 (2019). https://doi.org/10.1134/S0022476619070072
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476619070072