Abstract
In the interaction of scandium chloride hexahydrate and 2,5-pyrazinedicarboxylic acid (H2pzc) dihydrate in different solvent mixtures two novel coordination polymers are obtained under solvothermal conditions: [Sc2(dmf)2(H2O)2(pzc)3] (1) and [Sc2(H2O)2(pzc)3]·2CH3CN·H2O (2) (dmf is N,N-dimethylformamide). Crystal structures of compounds 1 and 2 are determined by single crystal X-ray diffraction and supported by elemental and thermogravimetric data and IR spectroscopy. The phase purity of the samples prepared is confirmed by powder X-ray diffraction. It is shown that the coordination environment of the scandium cation and the 2,5-pyrazinedicarboxylate ligand denticity change depending on the composition of a solvent mixture. Compound 1 has a layered structure while in the structure of 2 there is a three-dimensional framework.
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D. N. Dybtsev, A. A. Sapianik, and V. P. Fedin. Mendeleev Commun., 2017, 4, 321.
A. A. Sapianik, E. E. Semenenko, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. J. Struct. Chem., 2018, 59, 487.
L. Jiao, Y. Wang, H.-L. Jiang, and Q. Xu. Adv. Mater., 2018, 30, 1703663.
M. Cheng, C. Lai, Y. Liu, G. Zeng, D. Huang, C. Zhang, L. Qin, L. Hu, C. Zhou, and W. Xiong. Cood. Chem. Rev., 2018, 368, 80.
J.-R. Li, J. Sculley, and H.-C. Zhou. Chem. Rev., 2012, 112, 869.
H. Li, K. Wang, Y. Sun, C. T. Lollar, J. Li, and H.-C. Zhou. Mater. Today, 2018, 21, 108.
E. S. Sanz-Perez, C. R. Murdock, S. A. Didas, and C. W. Jones. Chem. Rev., 2016, 116, 11840.
G. Minguez Espallargas and E. Coronado. Chem. Soc. Rev., 2018, 47, 533.
F. Maya, C. Palomino Cabello, R. M. Frizzarin, J. M. Estela, G. Turnes Palomino, and V. Cerda. TrAC Trend. Anal. Chem., 2017, 90, 142.
Y. Zhang, S. Yuan, G. Day, X. Wang, X. Yang, and H.-C. Zhou. Coord. Chem. Rev., 2018, 354, 28.
W. P. Lustig, S. Mukherjee, N. D. Rudd, A. V. Desai, J. Li, and S. K. Gosh. Chem. Soc. Rev., 2017, 46, 3242.
S. Yuan, L. Feng, K. Wang, J. Pang, M. Bosch, C. Lollar, Y. Sun, J. Qin, X. Yang, P. Zhang, Q. Wang, L. Zou, Y. Zhang, Y. Fang, J. Li, and H.-C. Zhou. Adv. Mater., 2018, 30, 1704303.
M. O. Barsukova, S. A. Sapchenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Rev., 2018, 87, 1139.
A. M. Cheplakova, I. S. Fedoseev, P. V. Dorovatovskii, V. A. Lazarenko, Ya. V. Zubavichus, V. N. Khrustalev, and V. P. Fedin. J. Struct. Chem., 2018, 59, 494.
M. O. Barsukova, D. G. Samsonenko, A. A. Sapianik, S. A. Sapchenko, and V. P. Fedin. Polyhedron, 2018, 144, 219.
CrysAlisPro 1.171.38.41. Rigaku Oxford Diffraction, 2015.
G. M. Sheldrick. Acta Crystallogr. A, 2015, 71, 3.
G. M. Sheldrick. Acta Crystallogr. C, 2015, 71, 3.
A. L. Spek. Acta Crystallogr. D, 2009, 65, 148.
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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 5, pp. 857-863.
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Barsukova, M.O., Sapianik, A.A., Samsonenko, D.G. et al. Crystal Structure of Coordination Polymers Based on Scandium and 2,5-Pyrazinedicarboxylic Acid. J Struct Chem 60, 823–829 (2019). https://doi.org/10.1134/S0022476619050160
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DOI: https://doi.org/10.1134/S0022476619050160