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Molecular and Crystal Structure of (1S,2R)-1-{2-[(1S)-1-(Dimethylamino)Ethyl]Phenyl}-1,2-Diphenylethane-1,2-Diol

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Abstract

The (R)-configuration of the carbinol center formed as a result of diastereospecific reduction of (2S)-2-{2-(1S)-1-(dimethylamino)ethyl]phenyl}-2-hydroxy-1,2-diphenylethanone is established by the XRD method. The analysis of shortened nonvalent intramolecular contacts testifies that the molecule is quite rigid, despite the presence of a large number of single valence bonds. Layered nature of molecular packaging is revealed.

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Authors and Affiliations

  1. Moscow State University, Moscow, Russia

    V. M. Demyanovich & I. N. Shishkina

  2. Vladimir State University, Vladimir, Russia

    K. A. Potekhin, A. V. Maleev & A. A. Gevorgyan

Authors
  1. V. M. Demyanovich
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  2. I. N. Shishkina
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  3. K. A. Potekhin
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  4. A. V. Maleev
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  5. A. A. Gevorgyan
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Corresponding author

Correspondence to A. V. Maleev.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 4, pp. 680–687.

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Demyanovich, V.M., Shishkina, I.N., Potekhin, K.A. et al. Molecular and Crystal Structure of (1S,2R)-1-{2-[(1S)-1-(Dimethylamino)Ethyl]Phenyl}-1,2-Diphenylethane-1,2-Diol. J Struct Chem 60, 654–661 (2019). https://doi.org/10.1134/S0022476619040176

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  • DOI: https://doi.org/10.1134/S0022476619040176

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