Abstract
The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF1+x coated by an outer nanolayer sp2-C–sp3-C–F.
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Original Russian Text © 2018 V. N. Mitkin, I. P. Asanov, A. K. Sagidullin.
Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 8, pp. 1904–1911, November-December, 2018.
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Mitkin, V.N., Asanov, I.P. & Sagidullin, A.K. An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites. J Struct Chem 59, 1841–1848 (2018). https://doi.org/10.1134/S0022476618080127
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DOI: https://doi.org/10.1134/S0022476618080127