Skip to main content
SpringerLink
Log in

Hirshfeld Surface Analysis, Crystal Structure and Spectroscopic Studies of a New Cu(II) Halocuprate Salt with Protonated N-Amino-Ethyl-Piperazine

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

(C6H18N3)4[CuCl5]2[CuCl4]3·1.42H2O is prepared and characterized by various physicochemical techniques. The single crystal X-ray diffraction structural analysis reveals that the title compound belongs to the orthorhombic system with the space group Cmca. Its unit cell dimensions are: a = 24.286(2) Å, b = 14.3082(14) Å, c = 16.6160(16) Å, Z = 4, V = 5773.8(10) Å3. Its crystal structure is determined and refined down to R = 0.024 and wR(F2) = 0.059. The structure contains three crystallographically independent Cu2+ ions coordinated to chlorine anions in various fashions. Cu1 is five-coordinated in a distorted square pyramidal fashion, while Cu2 and Cu3 are four-coordinated in square planar and distorted tetrahedral fashions, respectively. The entities are interconnected by means of the hydrogen bonding [O(W)–H…Cl, N–H…Cl, C–H…Cl and C–H…O(W)], forming a three-dimensional network. Intermolecular interactions are investigated by Hirshfeld surfaces and the contacts of the eight different chloride atoms are notably compared. The vibrational absorption bands are identified by infrared spectroscopy. The optical study is performed by UV-vis absorption.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. D. Martin and B. R. Leafblad. Angew. Chem., 1998, 37, 3318–3320.

    Article  CAS  Google Scholar 

  2. C. R. Rice, S. Onions, N. Vidal, J. D. Wallis, M.-C. Senna, M. Pilkington, and H. Stoeckli-Evans. Eur. J. Inorg. Chem., 2002, 8, 1985–1997.

    Article  Google Scholar 

  3. R. Bhattacharya, M. S. Ray, R. Dey, L. Righi, G. Bocelli, and A. Ghosh. Polyhedron, 2002, 21, 2561–2565.

    Article  CAS  Google Scholar 

  4. A. Weselucha-Birczynska and C. Paluszkiewicz. J. Mol. Struct., 2002, 614, 339–343.

    Article  CAS  Google Scholar 

  5. S. F. Haddad, M. A. AlDamen, and R. D. Willet. Inorg. Chim. Acta, 2006, 359, 424–432.

    Article  CAS  Google Scholar 

  6. A. R. Parent, C. P. Landee, and M. M. Turnbull. Inorg. Chim. Acta, 2007, 360, 1943–1953.

    Article  CAS  Google Scholar 

  7. F. A. Cotton, L. M. Daniels, and P. I. Huang. Inorg. Chem., 2001, 40, 3576–3578.

    Article  CAS  PubMed  Google Scholar 

  8. M. Czugler, L. Kótai, B. Sreedhar, A. Rockenbauer, I. Gács, and S. Holly. Eur. J. Inorg. Chem., 2002, 12, 3298–3304.

    Article  Google Scholar 

  9. N. Lah and R. Clérac. Polyhedron, 2009, 28, 2466–2472.

    Article  CAS  Google Scholar 

  10. B. J. Prince, M. M. Turnbull, and R. D. Willett. J. Coord. Chem., 2003, 56, 441–452.

    Article  CAS  Google Scholar 

  11. S. N. Herringer, M. M. Turnbull, C. P. Landee, and J. L. Wikaira. J. Coord. Chem., 2009, 62, 863–875.

    Article  CAS  Google Scholar 

  12. M. Zdanowska-Fraczek, K. Holderna-Natkaniec, Z. J. Fraczek, and R. Jakubas. Solid State Ion, 2009, 180, 9–12.

    Article  CAS  Google Scholar 

  13. I. Chaabane, F. Hlel, and K. Guidara. J. Alloys Compd., 2008, 461, 495–500.

    Article  CAS  Google Scholar 

  14. K. Sakai, M. Takemura, and Y. Kawabe. J. Lumin., 2010, 130, 2505–2507.

    Article  CAS  Google Scholar 

  15. K. Pradeesh, G. Sharachandar Yadav, M. Singh, and G. Vijaya Prakash. J. Mater. Chem. Phys., 2010, 124, 44–47.

    Article  CAS  Google Scholar 

  16. M. Bujak and J. Zaleski. Cryst. Eng., 2001, 4, 241–252.

    Article  CAS  Google Scholar 

  17. P. Gomez-Romero. Adv. Mater., 2001, 13, 163–174.

    Article  CAS  Google Scholar 

  18. John R. J. Sorenson. J. Med. Chem., 1976, 19, 135–148.

    Article  CAS  PubMed  Google Scholar 

  19. P. M. May and D. R. Williams. Met. Ions Biol. Syst., Helmut Sigel: New York, USA, 1981, 12, 283–317.

    CAS  Google Scholar 

  20. P. S. Subramanian and D. Srinivas. Polyhedron, 1996, 15, 985–989.

    Article  CAS  Google Scholar 

  21. J. Sertucha, A. Luque, F. Lloret, and P. Román. Polyhedron, 1998, 17, 3875–3880.

    Article  CAS  Google Scholar 

  22. V. Fernandez, M. Moran, M. T. Gutiérrez-Rios, C. Foces-Foces, and F. H. Cano. Inorg. Chim. Acta, 1987, 128, 239–243.

    Article  CAS  Google Scholar 

  23. P. Román, J. Sertucha, A. Luque, L. Lezama, and T. Rojo. Polyhedron, 1996, 15, 1253–1262.

    Article  Google Scholar 

  24. K. M. Guckian, B. A. Schweitzer, R. X. Ren, C. J. Sheils, D. C. Tahmassebi, and E. T. Kool. J. Am. Chem. Soc., 2000, 122, 2213–2222.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  25. Bruker Apex2, Advanced X-ray Solutions Bruker AXS Inc. Madison, Wisconsin, USA, 2009.

  26. G. M. Sheldrick. Acta Crystallogr., 2008, A64, 112–122.

    Article  CAS  Google Scholar 

  27. Bruker Advanced X-ray Solutions, SHELXTL (Version 6.14), Bruker AXS Inc. Madison, Wisconsin, USA, 2003.

  28. G. M. Sheldrick. SHELXL2013, University of Göttingen, Germany, 2013.

    Google Scholar 

  29. C. B. Hübschle, G. M. Sheldrick, and B. Dittrich. J. Appl. Crystallogr., 2011, 44, 1281–1284.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  30. K. Brandenburg. Diamond Version 2.0 Impact GbR, Bonn., Germany, 1998.

    Google Scholar 

  31. L. Yang, D. R. Powell, and R. P. Houser. Dalton Trans., 2007, 955–964.

    Google Scholar 

  32. A. Kessentini, M. Belhouchet, Y. Abid, C. Minot, and T. Mhiri. Spectrochim. Acta A, 2014, 122, 476–481.

    Article  CAS  Google Scholar 

  33. D.-H. He, Y.-Y. Di, Z.-C. Tan, F.-F. Yi, W.-Y. Dan, and Y.-P. Liu. Sol. Energy Mater. Sol. Cells, 2011, 95, 2897–2906.

    Article  CAS  Google Scholar 

  34. E. P. Aldrich, K. A. Bussey, J. R. Connell, E. F. Reinhart, K. D. Oshin, B. Q. Mercado, and A. G. Oliver. Acta Crystallogr., 2016, E72, 40–43.

    Google Scholar 

  35. A. Kessentini, M. Belhouchet, J. J. Suñol, Y. Abid, and T. Mhiri. J. Lumin., 2014, 149, 341–347.

    Article  CAS  Google Scholar 

  36. G. R. Willey, M. Ravindran, and M. G. B. Drew. Inorg. Chim. Acta, 1991, 188, 159–162.

    Article  CAS  Google Scholar 

  37. A. W. Addison, T. Nageswara Rao, J. Recdijk, J. van Rijn, and G. C. Verschoor. J. Chem. Soc., Dalton Trans., 1984, 1349–1356.

    Google Scholar 

  38. D. Cremer. J. Am. Chem. Soc., 1975, 97, 1354–1358.

    Article  CAS  Google Scholar 

  39. M. A. Spackman and D. Jayatilaka. CrystEngComm, 2009, 11, 19–32.

    Article  CAS  Google Scholar 

  40. B. Guillot, E. Enrique, L. Huder, and C. Jelsch. Acta Crystallogr., 2014, A70, C279.

    Google Scholar 

  41. C. Jelsch, S. Soudani, and C. Ben Nasr. IUCrJ, 2015, 2, 327–340.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  42. S. Gunasekaran and B. Anita. Indian J. Pure Appl. Phys., 2008, 46, 833–838.

    CAS  Google Scholar 

  43. J. Orive, E. S. Larrea, R. F. De Luis, M. Iglesias, J. L. Mesa, T. Rojo, and M. I. Arriortua. Dalton Trans., 2013, 42, 4500–4512.

    Article  CAS  PubMed  Google Scholar 

  44. P. F. Raphael, E. Manoj, and M. R. P. Kurup. Polyhedron, 2007, 26, 818–828.

    Article  CAS  Google Scholar 

  45. B. F. Hathaway. In Comprehensive Coordination Chemistry /Ed. G. Wilkinson. Pergamon, Oxford, 1st edn., 1987, 5, 533–774.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, Zarzouna, Tunisia

    Maroua El Glaoui & C. Ben Nasr

  2. Laboratoire de Valorisation des Matériaux Utiles, Centre National des Recherches en Sciences des Matériaux (CNRSM), Technopôle de Borj-Cédria, Soliman, Tunisia

    Maher El Glaoui

  3. CRM2, CNRS, Institut Jean Barriol, Université de Lorraine, Vandoeuvre les Nancy, France

    C. Jelsch

Authors
  1. Maroua El Glaoui
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Maher El Glaoui
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. Jelsch
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. C. Ben Nasr
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Maher El Glaoui.

Additional information

Original Russian Text © 2018 Maroua El Glaoui, Maher El Glaoui, C. Jelsch, C. Ben Nasr.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 7, pp. 1669–1677, September-October, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

El Glaoui, M., El Glaoui, M., Jelsch, C. et al. Hirshfeld Surface Analysis, Crystal Structure and Spectroscopic Studies of a New Cu(II) Halocuprate Salt with Protonated N-Amino-Ethyl-Piperazine. J Struct Chem 59, 1610–1618 (2018). https://doi.org/10.1134/S0022476618070120

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476618070120

Keywords

Search

Navigation