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Structure and Photocatalytic Properties of a 3D Zinc(II) Triazolate Coordination Polymer Combining Hydroxyl and Formate Anions as the Auxiliary Coligands

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Abstract

A new 3D zinc coordination polymer, namely {[Zn4(dmtz)3(OH)3(HCOO)](NO3)}n (1, Hdmtz = 3,5- dimethyl-1,2,4-triazole), is hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, and single crystal X-ray diffraction analysis. The complex features a (3,4,5)- connected 3D cation framework constructed by μ3-bridging dmtz with hydroxyl and formate anions as the auxiliary ligands. Moreover, the photocatalytic properties of 1 are also investigated.

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References

  1. R. B. Getman, Y. S. Bae, C. E. Wilmer, et al. Chem. Rev., 2012, 112, 703.

    Article  CAS  PubMed  Google Scholar 

  2. B. V. Voorde, B. Bueken, J. Denayerb, et al. Chem. Soc. Rev., 2014, 43, 5766.

    Article  PubMed  Google Scholar 

  3. J. R. Li, J. Sculley, and H.–C. Zhou. Chem. Rev., 2012, 112, 869.

    Article  CAS  PubMed  Google Scholar 

  4. C. K. Brozek and M. Dincǎ. Chem. Soc. Rev., 2014, 43, 5456.

    Article  CAS  PubMed  Google Scholar 

  5. J. Liu, L. Chen, H. Cui, et al. Chem. Soc. Rev., 43, 2014, 6011.

    Google Scholar 

  6. W. X. Zhang, P. Q. Liao, R. B. Lin, et al. Coord. Chem. Rev., 2015, 293/294, 263.

    Google Scholar 

  7. Z. Hu, B. J. Deibert, and J. Li. Chem. Soc. Rev., 2014, 43, 5815.

    Article  CAS  PubMed  Google Scholar 

  8. J. P. Zhang, Y. B. Zhang, J. B. Lin, et al. Chem. Rev., 2012, 112, 1001.

    Article  CAS  PubMed  Google Scholar 

  9. A. X. Zhu, J. B. Lin, J. P. Zhang, et al. Inorg. Chem., 2009, 48, 3882.

    Article  CAS  PubMed  Google Scholar 

  10. A. X. Zhu, Y. Liu, and W. X. Zhang. Inorg. Chem. Commun., 2013, 30, 88.

    Article  CAS  Google Scholar 

  11. Q. G. Zhai, X. Y. Wu, S. M. Chen, et al. Cryst. Growth Des., 2006, 6, 2126.

    Article  CAS  Google Scholar 

  12. W. Ouellette, A. V. Prosvirin, J. Valeich, et al. Inorg. Chem., 2007, 46, 9067.

    Article  CAS  PubMed  Google Scholar 

  13. C. Y. Su, Y. Z. Tong, F. C. Yuan, et al. Inorg. Chim. Acta, 2014, 423a, 545.

    Google Scholar 

  14. S. Ferrer, F. Lloret, I. Bertomeu, et al. Inorg. Chem., 2002, 41, 5821.

    Article  CAS  PubMed  Google Scholar 

  15. M. Li, Y. F. Peng, S. Zhao, et al. RSC Adv., 2014, 4, 14241.

    Article  CAS  Google Scholar 

  16. Y. F. Peng, S. Zhao, K. Li, et al. CrystEngComm, 2015, 17, 2544.

    Article  CAS  Google Scholar 

  17. S. Zhao, T. R. Zheng, Y. Q. Zhang, et al. Polyhedron, 2017, 121, 61.

    Article  CAS  Google Scholar 

  18. X. X. Lu, Y. H. Luo, Y. S. Liu, et al. CrystEngComm, 2016, 18, 3650.

    Article  CAS  Google Scholar 

  19. Y. M. Chen, Y. H. Yu, H. Z. Zhang, et al. CrystEngComm, 2016, 18, 6389.

    Article  CAS  Google Scholar 

  20. E. L. Zhou, C. Qin, X. L. Wang, et al. CrystEngComm, 2016, 18, 6370.

    Article  CAS  Google Scholar 

  21. X. L. Wang, C. H. Gong, J. W. Zhang, et al. CrystEngComm, 2015, 17, 4179.

    Article  CAS  Google Scholar 

  22. X. L. Wang, C. H. Gong, J. W. Zhang, et al. CrystEngComm, 2014, 16, 7745.

    Article  CAS  Google Scholar 

  23. Z. Zhang, J. Yang, Y. Y. Liu, et al. CrystEngComm, 2013, 15, 3843.

    Article  CAS  Google Scholar 

  24. H. M. Zhang, J. Yang, W. Q. Kan, et al. Cryst. Growth Des., 2016, 16, 265.

    Article  CAS  Google Scholar 

  25. A. X. Zhu, Q. Q. Xu, F. Y. Liu, et al. Inorg. Chim. Acta, 2011, 370, 333.

    Article  CAS  Google Scholar 

  26. A. X. Zhu, Q. Q. Xu, F. Y. Liu, et al. Z. Anorg. Allg. Chem., 2011, 637, 502.

    Article  CAS  Google Scholar 

  27. G. A. V. Albada, R. A. G. D. Graaff, J. G. Haasnoot, et al. Inorg. Chem., 1984, 23, 1404.

    Article  Google Scholar 

  28. G. M. Sheldrick. Acta Crystallogr. Sect. C: Struct. Chem., 2015, C71, 3.

    Google Scholar 

  29. A. W. Addison, T. N. Rao, J. Reedijk, et al. J. Chem. Soc., Dalton Trans., 1984, 1349.

    Google Scholar 

  30. W. Y. Yin, Z. L. Huang, X. Y. Tang, et al. New J. Chem., 2015, 39, 7130.

    Article  CAS  Google Scholar 

  31. S. Zhao, Y. Q. Zhang, T.–R. Zheng, et al. Inorg. Chem. Commun., 2016, 73, 134.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming, P. R. China

    X.-D. Fang, L.-B. Yang, A.-N. Dou, A.-X. Zhu & Q.-Q. Xu

Authors
  1. X.-D. Fang
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  2. L.-B. Yang
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  3. A.-N. Dou
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  4. A.-X. Zhu
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  5. Q.-Q. Xu
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Corresponding author

Correspondence to A.-X. Zhu.

Additional information

Original Russian Text © 2018 X.-D. Fang, L.-B. Yang, A.-N. Dou, A.-X. Zhu, Q.-Q. Xu.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1503–1507, July-August, 2018.

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10947_2018_1019_MOESM1_ESM.pdf

Supplementary Materials to: Structure and Photocatalytic Properties of a 3D Zinc(II) Triazolate Coordination Polymer Combining Hydroxyl and Formate Anions as the Auxiliary Coligands

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Fang, XD., Yang, LB., Dou, AN. et al. Structure and Photocatalytic Properties of a 3D Zinc(II) Triazolate Coordination Polymer Combining Hydroxyl and Formate Anions as the Auxiliary Coligands. J Struct Chem 59, 1450–1455 (2018). https://doi.org/10.1134/S002247661806029X

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  • DOI: https://doi.org/10.1134/S002247661806029X

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