Skip to main content
SpringerLink
Log in

Crystal Structures, Magnetic Properties, and Theoretical Investigations of Three Linear Cluster Complexes with Pyridine-2-Amidoxime

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Three novel trinuclear mixed-transition-metal complexes of Fe(III), Co(III, II), Ni(II) and Cr(III)), with pyridine-2-amidoxime (Hpa) ligand are synthesized, i.e. [FeNi2(pa)6]Cl·15H2O (1), [CrNi2(pa)6]OH·5H2O (2), and [CoCo2(pa)6]NO3 (3). These complexes are characterized by variable-temperature magnetic susceptibility, electrochemistry, and single crystal X-ray diffraction methods. 1 and 2 are heteronuclear metal clusters in the perfect linear arrangement, i.e. [NiII⋯FeIII⋯NiII and [NiII⋯CrIII⋯NiII] respectively, while 3 is linear [CoII⋯CoIII⋯CoII] trinuclear. Theoretical calculations are employed to successfully account for the experimental results of the variable temperature magnetic susceptibility.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. P. Yang, C. Y. Shao, Y. Xu, and L. L. Zhu. Z. Anorg. Allg. Chem., 2013, 639, 548–551.

    Article  CAS  Google Scholar 

  2. M. Wang, C. B. Ma, D. Q. Yuan, et al. Inorg. Chem., 2008, 47, 5580–5590.

    Article  CAS  PubMed  Google Scholar 

  3. G. Piotr, J. Jan, D. Marek, and Z. Jerzy.Polyhedron, 2014, 81, 132–141.

    Article  CAS  Google Scholar 

  4. M. Nihei, A. Yoshida, S. Koizumi, and H. Oshio. Polyhedron, 2007, 26, 1997–2007.

    Article  CAS  Google Scholar 

  5. L. Guido, D. Serhiy, B. S. Bernhard, et al. Eur. J. Inorg. Chem., 2004, 2413–2420.

    Google Scholar 

  6. E. Manoj, M. R. Kurup, H. K. Fun, and A. Punnoose. Polyhedron, 2007, 26, 4451–4462.

    Article  CAS  Google Scholar 

  7. Hajinasiri and M. A. Khalilzadeh. Chin. Chem. Lett., 2012, 512–514.

    Google Scholar 

  8. X. M. Chen and M. L. Tong. Acc. Chem. Res., 2007, 40, 162–170.

    Article  CAS  PubMed  Google Scholar 

  9. M. S. Lah and V. Pecoraro. J. Am. Chem. Soc., 1989, 111, 7258/7259.

    Article  CAS  Google Scholar 

  10. B. R. Gibney, H. Wang, J. W. Kampf, and V. L. Pecoraro. Inorg. Chem., 1996, 35, 6184–6193.

    Article  CAS  Google Scholar 

  11. C. J. Milios, R. Inglis, A. Vinslava, et al. Chem. Commun., 2007, 2738–2740.

    Google Scholar 

  12. G. A. Pearse, P. R. Ratithby, C. M. Hay, and J. Lewis. Polyhedron, 1989, 8, 301–304.

    Article  CAS  Google Scholar 

  13. C. P. Raptopoulou and V. Psycharis. Inorg. Chem. Commun., 2008, 11, 1194–1197.

    Article  CAS  Google Scholar 

  14. T. C. Stamatatos, A. Bell, P. Cooper, et al. Inorg. Chem. Commun., 2005, 8533–538.

    Google Scholar 

  15. J. Gradinaru, S. Malinovskii, M. Gdaniec, and S. Zecchin. Polyhedron, 2006, 25, 3417–3426.

    Article  CAS  Google Scholar 

  16. J. W. Ran, X. Y. Li, Q. D. Zhao, and G. H. Chen. Inorg. Chem. Commun., 2010, 13, 1527–1529.

    Article  CAS  Google Scholar 

  17. J. W. Ran, S. W. Liu, P. Wu, and J. Pei. Chin. Chem. Lett., 2013, 24, 373–375.

    Article  CAS  Google Scholar 

  18. E. Bernasek. J. Organ. Chem., 1957, 22, 1263/1264.

    Article  CAS  Google Scholar 

  19. A. P. Ginsberg. Inorg. Chim. Acta, 1971, 5, 45–49.

    Article  CAS  Google Scholar 

  20. G. M. Sheldrick. SHELXS 97, Program for the solution of crystal structures. University of Gottingen, Germany, 1997.

    Google Scholar 

  21. G. M. Sheldrick. SHELXL 97, Program for the refinement of crystal structures. University of Gottingen, Germany, 1997.

    Google Scholar 

  22. T. Weyhermüller, R. Wagner, S. Khanra, and P. Chaudhuri. Dalton Trans., 2005, 2539–2546.

    Google Scholar 

  23. F. Birkelbach, U. Florke, H.–J. Haupt, C. Butzlaff, A. X. Trautwein, K. Wieghardt, and P. Chaudhuri. Inorg. Chem., 1998, 37, 2000–2008.

    Article  CAS  Google Scholar 

  24. F. Tuyeras, A. Scuiller, C. Duhayon, et al. Inorg. Chim. Acta, 2008, 361, 3505–3518.

    Article  CAS  Google Scholar 

  25. H.–Z. Kou, G.–Y. An, C.–M. Ji, et al. Dalton Trans., 2010, 39, 9604–9610.

    Article  CAS  PubMed  Google Scholar 

  26. G.–Y. An, B. Yuan, J. Tao, et al. Inorg. Chim. Acta, 2012, 387, 401–406.

    Article  CAS  Google Scholar 

  27. B. Delley. J. Chem. Phys., 1990, 92, 508–517.

    Article  CAS  Google Scholar 

  28. B. Delley. J. Chem. Phys., 2000, 113, 7756–7764.

    Article  CAS  Google Scholar 

  29. P. Chaudhuri, T. Weyhermu, R. Wagner, S. Khanra, B. Biswas, E. Bothe, and E. Bill. Inorg. Chem., 2007, 46, 9003–9016.

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry and Materials Engineering, Huizhou University, Huizhou, P. R. China

    Y.-P. Tong

  2. College of Chemical Engineering, Huanggang Normal University, Huanggang, P. R. China

    J.-W. Ran

  3. Hubei Key Laboratory for Processing and Application of Catalytic Materials, Huanggang, P. R. China

    J.-W. Ran

Authors
  1. J.-W. Ran
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y.-P. Tong
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J.-W. Ran.

Additional information

Original Russian Text © 2018 J.-W. Ran, Y.-P. Tong.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1486–1492, July-August, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ran, JW., Tong, YP. Crystal Structures, Magnetic Properties, and Theoretical Investigations of Three Linear Cluster Complexes with Pyridine-2-Amidoxime. J Struct Chem 59, 1433–1439 (2018). https://doi.org/10.1134/S0022476618060264

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476618060264

Keywords

Search

Navigation