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Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions: Synthesis of [SiW11O39{Ru(NO)}]5–

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Abstract

The thermostating of an aqueous solution of K2[Ru(NO)Cl5] and K8[γ-SiW10O36] at 160 °С for 16 h leads to a change in the color of the solution from pink to brown. According to the HPLC-ICP-AES data, the reaction products are Keggin anions: [SiW11O39{Ru(NO)}]5– (1) and [SiW12O40]4– (2). The formation of 1 and 2 is demonstrated by mass spectrometry for tetrabutylammonium salts in an acetonitrile solution. Red crystals of the composition ((CH3)2NH2)4H[α-SiW11O39{Ru(NO)}]·6H2O (1а) are obtained by fractional crystallization of dimethylammonium salts.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. A. Shmakova, V. V. Volchek, P. A. Abramov & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    A. A. Shmakova, V. V. Volchek, P. A. Abramov & M. N. Sokolov

Authors
  1. A. A. Shmakova
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  2. V. V. Volchek
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  3. P. A. Abramov
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  4. M. N. Sokolov
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Corresponding author

Correspondence to P. A. Abramov.

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Original Russian Text © 2018 A. A. Shmakova, V. V. Volchek, P. A. Abramov, M. N. Sokolov.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1480–1485, July-August, 2018.

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Shmakova, A.A., Volchek, V.V., Abramov, P.A. et al. Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions: Synthesis of [SiW11O39{Ru(NO)}]5–. J Struct Chem 59, 1427–1432 (2018). https://doi.org/10.1134/S0022476618060252

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  • DOI: https://doi.org/10.1134/S0022476618060252

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