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Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide

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Abstract

The structure of heterospin complexes[M(DCA)2L2x]·yH2O, where M = Mn, Co, Ni, Cu, Lx is the nitronyl nitroxide radical; DCA is the dicyanamide anion, y = 0, 1, or 2 is studied. It is found that the nature of[M(DCA)2L2x]·yH2O is characterized by the formation of multiple hydrogen bonds generating ribbons, layers, or frameworks in the crystals. The analysis of magnetostructural correlations by means of band calculations of the electronic structure confirms the occurrence of ferromagnetic exchange between the unpaired electrons of paramagnetic centers in solid [Cu(DCA)2L21]·2H2O when the distances between the copper ion and the coordinated N-O group are short.

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    G. V. Romanenko, E. Yu. Fursova, G. A. Letyagin, A. S. Bogomyakov, M. V. Petrova, V. A. Morozov & V. I. Ovcharenko

  2. Novosibirsk State University, Novosibirsk, Russia

    G. A. Letyagin, M. V. Petrova & V. A. Morozov

Authors
  1. G. V. Romanenko
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  2. E. Yu. Fursova
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  3. G. A. Letyagin
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  4. A. S. Bogomyakov
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  5. M. V. Petrova
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  6. V. A. Morozov
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  7. V. I. Ovcharenko
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Correspondence to G. V. Romanenko.

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Original Russian Text © 2018 G. V. Romanenko, E. Yu. Fursova, G. A. Letyagin, A. S. Bogomyakov, M. V. Petrova, V. A. Morozov, V. I. Ovcharenko.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1465–1473, July-August, 2018.

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Romanenko, G.V., Fursova, E.Y., Letyagin, G.A. et al. Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide. J Struct Chem 59, 1412–1420 (2018). https://doi.org/10.1134/S0022476618060239

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  • DOI: https://doi.org/10.1134/S0022476618060239

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