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Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes

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Abstract

In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Petrov & T. S. Sukhikh

  2. Novosibirsk State University, Novosibirsk, Russia

    P. A. Petrov & T. S. Sukhikh

Authors
  1. P. A. Petrov
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  2. T. S. Sukhikh
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Correspondence to P. A. Petrov.

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Original Russian Text © 2018 P. A. Petrov, T. S. Sukhikh.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1457–1464, July-August, 2018.

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Petrov, P.A., Sukhikh, T.S. Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes. J Struct Chem 59, 1405–1411 (2018). https://doi.org/10.1134/S0022476618060227

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  • DOI: https://doi.org/10.1134/S0022476618060227

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