Abstract
Crystal structures of CuInF5·7H2O and ZnGaF5·7H2O are determined. They are composed of centrosymmetric octahedral complex [Cu(1)(H2O)6]2+ and [Cu(2)(H2O)6]2+ ([Zn(1)(H2O)6]2+ and [Zn(2)(H2O)6]2+ respectively) cations and two types of centrosymmetric octahedral complex [In(1)F4(H2O)2]– and [In(2)F6]3– ([Ga(1)F4(H2O)2]– and [Ga(2)F6]3– respectively) anions. Coordinated H2O molecules in the complex [In(1)F4(H2O)2]– and [Ga(1)F4(H2O)2]– anions are in trans-positions. Branched systems of O–H...F and O–H...O hydrogen bonds organize the structural elements of the studied compounds into a three-dimensional framework. The unit cell parameters of some complex fluorides MIIAF5·7H2O (M = Co, Ni, Cu, Cd; A = In, Ga) are determined by X-ray diffraction of polycrystals and two isostructural series are identified.
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Original Russian Text © 2018 R. L. Davidovich, A. A. Udovenko, V. B. Logvinova, V. V. Tkachev, G. V. Shilov, T. A. Kaidalova.
Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1452–1456, July-August, 2018.
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Davidovich, R.L., Udovenko, A.A., Logvinova, V.B. et al. Single Crystal X-Ray Diffraction Study of Indium(III) and Gallium(III) Fluoride Complexes MIIAF5·7H2O (M = Co, Ni, Cu, Zn, Cd; A = In, Ga). J Struct Chem 59, 1400–1404 (2018). https://doi.org/10.1134/S0022476618060215
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DOI: https://doi.org/10.1134/S0022476618060215