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Structural Characterization of a Cu(I)/Br Complex with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands

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Abstract

The synthesis of a novel Cu(I) complex with V-shaped bidentate ligands {[Cu(BIPMO)]×[CuBr2]}n where BIPMO = bis(4-(1H-imidazol-1-yl)phenyl)methanone is reported. It is characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. Copper(I) ions in the complex are in a distorted environment in which donor atoms are provided by the bromide anion and nitrogen atoms of BIPMO ligands, respectively. Infinite anion chains formed by CuX4 (X = Br or N) polyhedra are linked by BIPMO ligands to give rise to layers. Furthermore, the layers are linked into 3D networks through weak intermolecular interactions.

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, Yuncheng, 044000, P. R. China

    S.-W. Sun & G.-F. Wang

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  1. S.-W. Sun
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  2. G.-F. Wang
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Correspondence to S.-W. Sun.

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Original Russian Text © 2018 S.-W. Sun, G.-F. Wang.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 766–769, March-April, 2018.

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Sun, SW., Wang, GF. Structural Characterization of a Cu(I)/Br Complex with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands. J Struct Chem 59, 744–747 (2018). https://doi.org/10.1134/S0022476618030381

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  • DOI: https://doi.org/10.1134/S0022476618030381

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