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Crystal Structure and Thermal Properties of a 2D Silver(I) Coordination Polymer with Semi-Rigid Bis(Pyrazole)

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Abstract

An Ag(I) coordination polymer [Ag2(L)2(H2btc)]n (L = 4,4′-bis(3,5-dimethylpyrazol-1-ylmethyl)-biphenyl, H4btc = 1,2,4,5-benzenetetracarboxylic acid) is hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, TGA analysis, and single crystal X-ray diffraction. It crystallizes in the triclinic space group Pī, a = 10.670(8) Å, b = 10.990(8) Å, c = 23.697(2) Å, α = 81.847(10), β = 82.171(10), γ = 80.592(10)°, V = 2695.5(3) Å3, Z = 2, Dcalc = 1.489 g/cm3, μ = 0.789 mm–1. The title compound displays a uninodal three-connected hcb/Shubnikov hexagonal plane with {63} topology, which is further extended into a 3D supramolecular framework via C–H···O interactions.

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Authors and Affiliations

  1. Journal Editorial Department, Hebei University of Environmental Engineering, Qinhuangdao, Hebei Province, P. R. China

    J. Cheng, G.-H. Wang & Y.-W. Wang

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  1. J. Cheng
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  2. G.-H. Wang
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  3. Y.-W. Wang
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Correspondence to J. Cheng.

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Original Russian Text © 2018 J. Cheng, G.-H. Wang, Y.-W. Wang.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 751–754, March-April, 2018.

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Cheng, J., Wang, GH. & Wang, YW. Crystal Structure and Thermal Properties of a 2D Silver(I) Coordination Polymer with Semi-Rigid Bis(Pyrazole). J Struct Chem 59, 729–732 (2018). https://doi.org/10.1134/S0022476618030356

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  • DOI: https://doi.org/10.1134/S0022476618030356

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