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Characterization and Crystal Structures of Oxovanadium(V) Complexes Derived from N′-(2-Hydroxybenzylidene)Pivalohydrazide

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Abstract

Two new oxovanadium(V) complexes [VOLL1] (1) and [VOLL2] (2) are prepared by the reaction of N′-(2-hydroxybenzylidene)pivalohydrazide (H2L) and [VO(acac)2] (where acac = acetylacetonate) with maltol (HL1) and 8-hydroxyquinoline (HL2), respectively, in methanol. Crystal and molecular structures of the complexes are determined by elemental analysis, infrared and electronic spectra, 1H NMR spectra, and single crystal X-ray diffraction. Complex 1 crystallizes in the monoclinic space group C2/c, with unit cell dimensions a = 15.828(2) Å, b = 22.412(3) Å, c = 12.873(3) Å, β = 121.256(5)°, V = 3903.7(12) Å3, Z = 8, GOOF = 1.036, R1 = 0.0554 and wR2 = 0.1302. Complex 2 crystallizes in the monoclinic space group P21/n, with unit cell dimensions a = 11.995(2) Å, b = 8.700(2) Å, c = 19.466(3) Å, β = 96.497(3)°, V = 2018.3(6) Å3, Z = 4, GOOF = 1.004, R1 = 0.0449 and wR2 = 0.0937. The V atoms are in the octahedral coordination.

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Authors and Affiliations

  1. School of Life Sciences, Shandong University of Technology, Zibo, P. R. China

    G.-H. Sheng & H.-L. Zhu

  2. Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, P. R. China

    A.-D. Liu, F.-Y. Liu, H. Liu, Y.-T. Ye & Z.-L. You

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  1. G.-H. Sheng
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  2. A.-D. Liu
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  3. F.-Y. Liu
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  4. H. Liu
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  5. Y.-T. Ye
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  6. Z.-L. You
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  7. H.-L. Zhu
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Correspondence to H.-L. Zhu.

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Original Russian Text © 2018 G.-H. Sheng, A.-D. Liu, F.-Y. Liu, H. Liu, Y.-T. Ye, Z.-L. You, H.-L. Zhu.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 726–729, March-April, 2018.

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Sheng, GH., Liu, AD., Liu, FY. et al. Characterization and Crystal Structures of Oxovanadium(V) Complexes Derived from N′-(2-Hydroxybenzylidene)Pivalohydrazide. J Struct Chem 59, 703–706 (2018). https://doi.org/10.1134/S0022476618030307

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  • DOI: https://doi.org/10.1134/S0022476618030307

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