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Crystal Structure of New Fluoride Complexes of Indium(III) M[Cu(H2O)4]InF6·nH2O (M = Rb, Cs, NH4; n = 0, 1)

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Abstract

Fluoride complexes of indium(III) with mixed monovalent M+ (M = Rb, Cs, NH4) and divalent [Cu(H2O)4]2+ cations of the composition M[Cu(H2O)4]InF6·nH2O (M = Rb, Cs, NH4; n = 0, 1) are synthesized for the first time and their crystal structures with a polymer chain character are studied. The structures of M[Cu(H2O)4]InF6·nH2O (M = Rb, Cs, NH4; n = 0, 1) are formed of monovalent Rb+, Cs+, NH4+ cations respectively, complex [Cu(H2O)4]2+ cations, slightly distorted octahedral complex [InF6]3– anions, and crystallization H2O molecules. By attaching one F atom from the neighboring InF6 groups, the [Cu(H2O)4]2+ cations form distorted octahedral Cu(H2O)4F2 groups. Via the bridging F atoms, the [Cu(H2O)4]2+ cations and [InF6]3– anions alternatively join into zigzag anionic polymer chains. A branched system of hydrogen O–H···F, O–H···Ow, and N–H···F bonds arrange the anionic chains into a threedimensional framework in whose voids the monovalent cations and crystallization H2O molecules are located. The structures of M[Cu(H2O)4]InF6·nH2O (M = Rb, Cs, NH4; n = 0, 1) are a new structure type.

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References

  1. R. L. Davidovich, P. P. Fedorov, and A. I. Popov. Rev. Inorg. Chem., 2016, 36(3), 105–133.

    Article  CAS  Google Scholar 

  2. R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, and G. V. Shilov. J. Struct. Chem., 2017, 58(3), 585–587.

    Article  CAS  Google Scholar 

  3. R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, and G. V. Shilov. J. Struct. Chem., 2017, 58(7), 1436–1439.

    Article  CAS  Google Scholar 

  4. R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, and G. V. Shilov. J. Struct. Chem., 2017, 58(1), 207–210.

    Article  CAS  Google Scholar 

  5. R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, and G. V. Shilov. J. Struct. Chem., 2017, 58(4), 813–816.

    Article  Google Scholar 

  6. R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, and G. V. Shilov. J. Struct. Chem., 2017, 58(1), 97–101.

    Article  CAS  Google Scholar 

  7. R. L. Davidovich. Atlas of Derivatograms of III–V Group Metal Fluoride Complexes [in Russian], Nauka, Moscow, 1976.

    Google Scholar 

  8. Yu. Ya. Kharitonov, R. L. Davidovich, and V. I. Kostin. Atlas of Far IR Spectra of Complex Fluorides of III–V Groups Metals and Uranyl [in Russian], Nauka, Moscow, 1977.

    Google Scholar 

  9. J. E. Roberts and A. W. Laubengayer. J. Am. Chem. Soc., 1957, 79(22), 5895–5897.

    Article  CAS  Google Scholar 

  10. Bruker. APEX II. Bruker AXS Inc. Madison, Wisconsin, USA, 2008.

  11. G. M. Sheldrick. SHELXTL. Bruker AXS Inc. Madison, Wisconsin, USA, 2000.

    Google Scholar 

  12. G. M. Sheldrick. Acta Crystallogr., 2008, A64(1), 112–122.

    Article  CAS  Google Scholar 

  13. A. Decian, J. Fischer, and R. Weiss. Acta Crystallogr., 1967, 22(3), 340–343.

    Article  CAS  Google Scholar 

  14. M. J. R. Clark, J. E. Fleming, and H. Lynton. Can. J. Chem., 1969, 47(20), 3859–3861.

    Article  CAS  Google Scholar 

  15. J. Fischer, G. Keib, and R. Weiss. Acta Crystallogr., 1967, 22(3), 338–340.

    Article  CAS  Google Scholar 

  16. J. Fischer and R. Weiss. Acta Crystallogr., 1973, B29(9), 1955–1957.

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia

    R. L. Davidovich, A. A. Udovenko & V. B. Logvinova

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    V. V. Tkachev & G. V. Shilov

Authors
  1. R. L. Davidovich
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  2. A. A. Udovenko
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  3. V. B. Logvinova
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  4. V. V. Tkachev
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  5. G. V. Shilov
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Correspondence to R. L. Davidovich.

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Original Russian Text © 2018 R. L. Davidovich, A. A. Udovenko, V. B. Logvinova, V. V. Tkachev, G. V. Shilov.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 674–678, March-April, 2018.

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Davidovich, R.L., Udovenko, A.A., Logvinova, V.B. et al. Crystal Structure of New Fluoride Complexes of Indium(III) M[Cu(H2O)4]InF6·nH2O (M = Rb, Cs, NH4; n = 0, 1). J Struct Chem 59, 652–656 (2018). https://doi.org/10.1134/S0022476618030216

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  • DOI: https://doi.org/10.1134/S0022476618030216

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