Skip to main content
SpringerLink
Log in

X-Ray Crystal Structure of a Novel 2D Mn(II) Coordination Polymer with 4,4′-trimethylenedipyridine and 3-nitrophthalate as Ligands

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

[Mn2(μ-4,4′-trimethylenedipyridine)(μ-3-nitrophthalate)2(H2O)4] n is synthesized using MnCl2·4H2O, 4,4′-trimethylenedipyridine, and 3-nitrophthalic acid as starting materials. The complex is investigated by Fourier transform infrared spectroscopy, single crystal X-ray diffraction, elemental analysis, powder X-ray diffraction, diffused reflectance spectroscopy, photoluminescent spectroscop, and thermogravimetric analysis. The complex crystallizes in the orthorhombic system in the space group Aba2 with cell parameters a = 30.1451(10) Å, b = 9.8718(3) Å, c = 11.3258(4) Å, V = 3370.40(19) Å3, and Z = 4. The complex exhibits a 2D structure with each Mn(II) atom octahedrally coordinated to three oxygen atoms from two 3-nitrophthalate units, two oxygen atoms from two water molecules, and one nitrogen atom from 4,4′- trimethylenedipyridine.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. J. Hong, J. S. Seo, J. Y. Ryu, J. H. Lee, C. Kim, S.-J. Kim, Y. Kim, and A. J. Lough, J. Mol. Struct., 22, 751 (2005).

    Google Scholar 

  2. C.-D. Wu, A. Hu, L. Zhang, and W. Lin, J. Am. Chem. Soc., 127, 8940 (2005).

    Article  CAS  Google Scholar 

  3. A. J. Fletcher, E. J. Cussen, D. Bradshaw, M. J. Rosseinsky, and K. M. Thomas, J. Am. Chem. Soc., 126, 9750 (2004).

    Article  CAS  Google Scholar 

  4. E.-Y. Choi, K. Park, C.-M. Yang, H. Kim, J.-H. Son, S. W. Lee, Y. H. Lee, D. Min, and Y.-U. Kwon, Chem. Eur. J., 10, 5535 (2004).

    Article  CAS  Google Scholar 

  5. K. S. Min and M. P. Suh, J. Am. Chem. Soc., 122, 6834 (2000).

    Article  CAS  Google Scholar 

  6. J. Fan, L. Gan, H. Kawaguchi, W.-Y. Sun, K.-B. Yu, and W.-X. Tang, Chem. Eur. J., 9, 3965 (2003).

    Article  CAS  Google Scholar 

  7. L. M. Toma, R. Lescouëzec, J. Pasán, C. Ruiz-Pérez, J. Vaissermann, J. Cano, R. Carrasco, W. Wernsdorfer, F. Lloret, and M. Julve, J. Am. Chem. Soc., 128, 4842 (2006).

    Article  CAS  Google Scholar 

  8. C. Jiao, F. Li, J. Zhang, Z. Li, S. Wang, Z. Wang, H. Yu, Z. Li, S. Liu, Z. Wang, X. Jiang, L. Sun, and F. Xu, Dalton Trans., 42, 1346 (2013).

    Article  CAS  Google Scholar 

  9. S. P. Jang, J. I. Poong, S. H. Kim, T. G. Lee, J. Y. Noh, C. Ki, Y. Kim, and S.-J. Kim, Polyhedron, 33, 194 (2012).

    Article  CAS  Google Scholar 

  10. M. Bremer, J. Sandstrom, P. Jeppson, B. Anderson, M. Kaderbhai, K. Orhan, S. Zinoveva, L. Shengming, D. L. Schulz, and A. N. Caruso, Polyhedron, 26, 2110 (2007)

    Article  CAS  Google Scholar 

  11. R. Wang, D. Yuan, F. Jiang, L. Han, S. Gao, and M. Hong, Eur. J. Inorg. Chem., 8, 1649 (2006).

    Article  Google Scholar 

  12. Bruker. APEX2, SAINT and SADABS, Bruker AXS Inc., Madison, Wisconsin, USA (2012).

  13. G. M. Sheldrick, Acta Crystallogr., A64, 112 (2008).

    Article  Google Scholar 

  14. X. Yu, S. Ni, D. Zhang, Y. Zheng, and H. Zhu, J. Mol. Struct., 1076, 426 (2014).

    Article  CAS  Google Scholar 

  15. C.-J. He, W.-Y. Wang, and Y.-F. Wang, Synth. React. Inorg., Met.-Org., Nano-Met. Chem., 44, 492 (2014).

    Article  CAS  Google Scholar 

  16. G.-L. Li, W.-D. Yin, G.-Z. Liu, L.-F. Ma, and L.-Y. Wang, J. Solid State Chem., 220, 1 (2014).

    Article  CAS  Google Scholar 

  17. S. Konar, S. C. Manna, E. Zangrando, T. Mallah, J. Ribas, and N. R. Chaudhuri, Eur. J. Inorg. Chem., 21, 4202 (2004).

    Article  Google Scholar 

  18. B. Li, G. Li, D. Liu, Y. Peng, X. Zhou, J. Hua, Z. Shi, and S. Feng, CrystEngComm, 13, 1291 (2011).

    Article  CAS  Google Scholar 

  19. M. Kalinowska, R. Świsłocka, and W. Lewandowski, J. Mol. Struct., 993, 404 (2011).

    Article  CAS  Google Scholar 

  20. R. P. Sharma, A. Saini, P. Venugopalan, J. Jezierska, and V. Ferretti, Inorg. Chem. Commun., 20, 209 (2012).

    Article  CAS  Google Scholar 

  21. G. B. Deacon, M. Forsyth, P. C. Junk, S. G. Leary, and W. W. Lee, Z. Anorg. Allg. Chem., 635, 833 (2009).

    Article  CAS  Google Scholar 

  22. F. Lian, R. Wang, L. Han, F. Jiang, and M. Hong, Z. Anorg. Allg. Chem., 631, 2485 (2005).

    Article  CAS  Google Scholar 

  23. X. Bu, Z. Wei, and S. Ren, J. Coord. Chem., 68, 471 (2014).

    Article  Google Scholar 

  24. Y.-E. Cha, X. Li, X. Ma, C.-Q. Wan, X.-B. Deng, and L.-P. Jin, CrystEngComm, 14, 5322 (2012).

    Article  CAS  Google Scholar 

  25. W. Li, P. T. Barton, R. P. Burwood, and A. K. Cheetham, Dalton Trans., 40, 7147 (2011).

    Article  CAS  Google Scholar 

  26. X. Ma, Y.-E. Cha, K. Zhao, X. Li, T.-T. Yan, X.-N. Liu, and L.-L. Feng, J. Coord. Chem., 65, 2500 (2012).

    Article  CAS  Google Scholar 

  27. C. N. R. Rao, S. Natarajan, and R. Vaidhyanathan, Angew. Chem. Int. Ed., 43, 1466 (2004).

    Article  CAS  Google Scholar 

  28. J. Zhao, X.-L. Wang, X. Shi, Q.-H. Yang, and C. Li, Inorg. Chem., 50, 3198 (2011).

    Article  CAS  Google Scholar 

  29. Y.-H. Xu, Y.-Q. Lan, X.-L. Wang, H.-Y. Zang, K.-Z. Shao, Y. Liao, and Z.-M. Su, Solid State Sci., 11, 635 (2009).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand

    S. Chooset & S. Wongnawa

  2. Department of Chemistry, Faculty of Science, Thaksin University, Papayom, Phatthalung, Thailand

    A. Kantacha

  3. Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, OH, USA

    A. Nimthong & M. Zeller

Authors
  1. S. Chooset
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Kantacha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Nimthong
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Zeller
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. Wongnawa
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Wongnawa.

Additional information

Original Russian Text © 2018 S. Chooset, A. Kantacha, A. Nimthong, M. Zeller, S. Wongnawa.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 217–224, January–February, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chooset, S., Kantacha, A., Nimthong, A. et al. X-Ray Crystal Structure of a Novel 2D Mn(II) Coordination Polymer with 4,4′-trimethylenedipyridine and 3-nitrophthalate as Ligands. J Struct Chem 59, 214–221 (2018). https://doi.org/10.1134/S0022476618010341

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476618010341

Keywords

Search

Navigation