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First Orotic Acid and Isonicotinic Acid Based Zn Complex: Hydrothermal Synthesis, Crystal Structure, and Thermogravimetric Analysis

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Abstract

New supramolecular synthon induced complex [Zn(Hor)(Hiso)·3H2O]·H2O (1) is obtained in a selfassembly reaction of zinc nitrate with orotic (H3Or, 1,2,3,6-tetrahydro-2,6-dioxo-4-pyrimidinecarboxylic) acid and isonicotinamide. The isonicotinamide molecule is hydrolyzed in-situ into isonicotinic (Hiso, pyridine-4-carboxylic) acid. A detailed structural analysis and the role of hydrogen bonding synthons in deciding the overall structural diversity is discussed. The {…H–N–C=O…}2 and {…H–O–C=O…}2 dimers play an important role in the metal-organic architecture of 1. Complex 1 is insoluble in almost all organic solvents as well as in water. The complete decomposition of the compound is achieved above 445°C.

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Authors and Affiliations

  1. Department of Chemistry, National Institute of Technology Raipur, G.E. Road Raipur, Chhattisgahr, India

    K. A. Siddiqui

  2. Department of Chemistry and Polymer Science, Stellenbosch University, Matieland, South Africa

    P. Lama

Authors
  1. K. A. Siddiqui
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  2. P. Lama
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Correspondence to K. A. Siddiqui.

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Original Russian Text © 2018 K. A. Siddiqui, P. Lama.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 170–175, January–February, 2018.

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Siddiqui, K.A., Lama, P. First Orotic Acid and Isonicotinic Acid Based Zn Complex: Hydrothermal Synthesis, Crystal Structure, and Thermogravimetric Analysis. J Struct Chem 59, 166–171 (2018). https://doi.org/10.1134/S0022476618010250

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