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Crystal Structure of Binuclear Cobalt Complexes [(Cp′′′Co)2(μ2-η1:η2-S2)2] and [(Cp′′′Co)2(μ2-η1:η2-Se2)2]

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Abstract

Binuclear cobalt complexes [(Cp′′′Co)2(μ2-η1:η2-S2)2] (1) (Cp′′′ = η5-1,2,4-tris(tert-butyl)cyclopentadienide) and [(Cp′′′Co)2(μ2-η1:η2-Se2)2] (2) are obtained by the interaction of [(Cp′′′Co)2(μ-η4:η4-C7H8)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. Yu. Afonin, T. S. Sukhikh & S. N. Konchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    T. S. Sukhikh & S. N. Konchenko

Authors
  1. M. Yu. Afonin
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  2. T. S. Sukhikh
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  3. S. N. Konchenko
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Corresponding author

Correspondence to S. N. Konchenko.

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Original Russian Text © 2018 M. Yu. Afonin, T. S. Sukhikh, S. N. Konchenko.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 140–143, January–February, 2018.

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Afonin, M.Y., Sukhikh, T.S. & Konchenko, S.N. Crystal Structure of Binuclear Cobalt Complexes [(Cp′′′Co)2(μ2-η1:η2-S2)2] and [(Cp′′′Co)2(μ2-η1:η2-Se2)2]. J Struct Chem 59, 136–139 (2018). https://doi.org/10.1134/S0022476618010201

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  • DOI: https://doi.org/10.1134/S0022476618010201

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