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Crystal Structure, Spectroscopic and Magnetic Properties of Trans-Difluoro-(1,4,8,11-Tetraazaundecane)Chromium(III) Aquatrichlorozincate

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An Erratum to this article was published on 01 March 2018

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Abstract

A new complex salt trans-[CrF2(2,3,2-tet)][ZnCl3(H2O)] (2,3,2-tet is 1,4,8,11-tetraazaundecane), is prepared and its structure is determined by single crystal X-ray diffraction using synchrotron data at 100 K. The complex crystallizes in the space group P21/c of the monoclinic system with two mononuclear formula units in a cell with dimensions a = 5.6360(11) Å, b = 17.120(3) Å, c = 17.020(3) Å, and β = 94.38(3)°. The chromium(III) ion is coordinated by four N atoms of the 2,3,2-tet ligand in the equatorial plane and two F atoms in a trans axial arrangement, displaying a slightly distorted octahedral geometry. The mean Cr–N(2,3,2-tet) and Cr–F bond distances are 2.0772(11) Å and 1.8930(8) Å, respectively. The crystal packing is stabilized by hydrogen bonding interactions between N–H groups of the 2,3,2-tet, O–H groups of the anion, the F atom, and the Cl atom of the anion. The FT-infrared, UV-visible spectra, and magnetic properties are also described.

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Change history

  • 02 June 2018

    In the original publication in Fig. 1 and the capture to it, an error was made. Fig. 1 should look like this.

References

  1. D. Yang and D. A. House, Inorg. Chem., 21, 2999–3007 (1982).

    Article  CAS  Google Scholar 

  2. D. A. House and D. Yang, Inorg. Chim. Acta, 74, 179–189 (1983).

    Article  CAS  Google Scholar 

  3. D. A. House and M. M. Turnbull, Inorg. Chim. Acta, 254, 401–405 (1997).

    Article  CAS  Google Scholar 

  4. H. R. Mäcke, B. F. Mentzen, J. P. Puaux, and A. W. Adamson, Inorg. Chem., 21, 3080–3082 (1982).

    Article  Google Scholar 

  5. E. Bang and E. Pedersen, Acta Chem. Scand., A32, 833–836 (1978).

    Article  CAS  Google Scholar 

  6. D. Moon and J.-H. Choi, Acta Crystallogr., Sect. E, 72, 424–427 (2016).

    Article  CAS  Google Scholar 

  7. J. H. Choi, H. S. Kim, and M. H. Habibi, Bull. Korean Chem. Soc., 29, 1399–1402 (2008).

    Article  CAS  Google Scholar 

  8. J. H. Choi, W. Clegg, and R. W. Harrington, Z. Anorg. Allg. Chem., 637, 562–566 (2011).

    Article  CAS  Google Scholar 

  9. J. H. Choi and U. Lee, Acta Crystallogr., Sect. E, 64, m1186 (2008).

    Article  CAS  Google Scholar 

  10. J. H. Choi and D. Moon, J. Mol. Struct., 1059, 325–331 (2014).

    Article  CAS  Google Scholar 

  11. L. Ronconi and P. J. Sadler, Coord. Chem. Rev., 251, 1633–1648 (2007).

    Article  CAS  Google Scholar 

  12. A. Ross, J.-H. Choi, T. M. Hunter, C. Pannecouque, S. A. Moggach, S. Parsons, E. De Clercq, and P. J. Sadler, Dalton Trans., 41, 6408–6418 (2012).

    Article  CAS  PubMed  Google Scholar 

  13. L. Fabbrizzi and A. Poggi, Chem. Soc. Rev., 42, 1681–1699 (2013).

    Article  CAS  PubMed  Google Scholar 

  14. M. Boiocchi, A. Broglia, L. Fabbrizzi, N. Fusco, and C. Manga, Can. J. Chem., 92, 794–802 (2014).

    Article  CAS  Google Scholar 

  15. J. Glerup, J. Josephsen, K. Michelsen, E. Pedersen, and C. E. Schäffer, Acta Chem. Scand., 24, 247–254 (1970).

    Article  CAS  Google Scholar 

  16. J. W. Shin, K. Eom, and D. Moon, J. Synchrotron Radiat., 23, 369–373 (2016).

    Article  PubMed  Google Scholar 

  17. Z. Otwinowski and W. Minor, in: Methods in Enzymology, Vol. 276, Part A, C. W. Carter Jr. and R. M. Sweet (eds.), Academic Press, New York (1997), p. 307.

  18. G. M. Sheldrick, Acta Crystallogr., Sect. A, 64, 112 (2008).

    Article  CAS  PubMed  Google Scholar 

  19. G. M. Sheldrick, Acta Crystallogr., C71, 3–8 (2015).

    Google Scholar 

  20. J. H. Choi, M. A. Subhan, and S. W. Ng, Z. Anorg. Allg. Chem., 638, 433–437 (2012).

    Article  CAS  Google Scholar 

  21. J. H. Choi, W. Clegg, G. S. Nichol, S. H. Lee, Y. C. Park, and M. H. Habibi, Spectrochim. Acta, 68A, 796–801 (2007).

    Article  CAS  Google Scholar 

  22. J.-H. Choi and S. H. Lee, J. Mol. Struct., 932, 84–89 (2009)

    Article  CAS  Google Scholar 

  23. J.-H. Choi and S. H. Lee, J. Mol. Struct., 1109, 258 (2016).

    Article  CAS  Google Scholar 

  24. J.-H. Choi, Inorg. Chim. Acta, 362, 4231–4236 (2009).

    Article  CAS  Google Scholar 

  25. J.-H. Choi, I.-G. Oh, T. Suzuki, and S. Kaizaki, J. Mol. Struct., 694, 39–44 (2004).

    Article  CAS  Google Scholar 

  26. M. A. Subhan, J.-H. Choi, and S. W. Ng, Z. Anorg. Allg. Chem., 637, 2193–2197 (2011).

    Article  CAS  Google Scholar 

  27. J. V. Brenčič and I. Leban, Z. Anorg. Allg. Chem., 480, 213–219 (1981).

    Article  Google Scholar 

  28. J. W. Vaughn and R. D. Rogers, J. Crystallogr. Spectrosc. Res., 15, 281–287 (1985).

    Article  CAS  Google Scholar 

  29. J. H. Choi, I. G. Oh, K. S. Ryoo, W. T. Lim, Y. C. Park, and M. H. Habibi, Spectrochim. Acta, 65A, 1138–1143 (2006).

    Article  CAS  Google Scholar 

  30. J. Pons, J. Rius, and J. Ros, Inorg. Chim. Acta, 359, 379–382 (2006).

    Article  CAS  Google Scholar 

  31. H. Adamsky, AOMX program, University of Düsseldorf, Germany (1996)

    Google Scholar 

  32. H. Adamsky, T. Schönherr, and M. Atanasov, in: Comprehensive Coordination Chemistry II, Elsevier (2004), pp. 661–664, pp. 443-455.

    Google Scholar 

  33. J. H. Choi and P. E. Hoggard, Polyhedron, 11, 2399–2407 (1992).

    Article  CAS  Google Scholar 

  34. J. H. Choi, Y. P. Hong, and Y. C. Park, Spectrochim. Acta, 58A, 1599–1606 (2002).

    Article  CAS  Google Scholar 

  35. J.-H. Choi, Chem. Phys., 256, 29–35 (2000).

    Article  CAS  Google Scholar 

  36. J.-H. Choi, Spectrochim. Acta, 56A, 1653–1660 (2000).

    Article  CAS  Google Scholar 

  37. J.-H. Choi, I.-G. Oh, R. Linder, and T. Schönherr, Chem. Phys., 297, 7–12 (2004).

    Article  CAS  Google Scholar 

  38. P. E. Hoggard, Top. Curr. Chem., 171, 113–142 (1994).

    Article  CAS  Google Scholar 

  39. C. S. Williams, N. C. Miller, and J. A. Collins, Polyhedron, 27, 523–529 (2008).

    Article  CAS  Google Scholar 

  40. L. G. Vanquickenborne and A. Ceulemans, Coord. Chem. Rev., 48, 157–202 (1983).

    Article  CAS  Google Scholar 

  41. M. A. Subhan, H. Nakata, T. Suzuki, J. H. Choi, and S. Kaizaki, J. Lumin., 101, 307–315 (2003).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Pohang Accelerator Laboratory, POSTECH, Pohang, Republic of Korea

    D. Moon

  2. Department of Chemistry, Tokyo University of Science, Tokyo, Japan

    S. Tanaka & T. Akitsu

  3. Department of Chemistry, Andong National University, Andong, Republic of Korea

    J.-H. Choi

Authors
  1. D. Moon
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  2. S. Tanaka
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  3. T. Akitsu
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  4. J.-H. Choi
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Correspondence to J.-H. Choi.

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Original Russian Text © 2018 D. Moon, S. Tanaka, T. Akitsu, J.-H. Choi.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 92–100, January–February, 2018.

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Moon, D., Tanaka, S., Akitsu, T. et al. Crystal Structure, Spectroscopic and Magnetic Properties of Trans-Difluoro-(1,4,8,11-Tetraazaundecane)Chromium(III) Aquatrichlorozincate. J Struct Chem 59, 87–95 (2018). https://doi.org/10.1134/S0022476618010134

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  • DOI: https://doi.org/10.1134/S0022476618010134

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