Abstract
A polymeric dinuclear copper(II) complex with a Schiff base based on 3-formyl-4-hydroxy-6-methylpyrone and 1,3-diaminopropanol-2 is synthesized. The crystal structure of the complex is determined by single crystal XRD (CCDC No. 1518681). The magnetic properties of the complex are studied. A ferromagnetic exchange interaction between copper(II) ions is demonstrated.
Similar content being viewed by others
References
A. Gaspar, M. J. Matos, J. Garrido, et al., Chem. Rev., 114, 4960–4992 (2014).
R. S. Keri, S. Budagumpi, R. K. Pai, et al., Eur. J. Med. Chem., 78, 340–374 (2014).
A. Sytnik, D. Gormin, and M. Kasha, Proc. Natl. Acad. Sci. USA 91, No. 25, 11968–11972 (1994).
G. Estiú, J. Rama, A. Pereira, et al., J. Mol. Struct. (TEOCHEM.), 487, 221–230 (1999).
T. C. Swinney and D. F. Kelley, J. Chem. Phys., 99, 211–221 (1993).
V. A. Kogan, V. V. Lukov, and I. N. Shcherbakov, Russ. J. Coord. Chem. 36, 401–429 (2010).
V. V. Lukov, V. A. Kogan, and S. I. Levchenkov, Russ. J. Coord. Chem. 41, 1–15 (2015).
S. I. Levchenkov, I. N. Shcherbakov, L. D. Popov, et al., J. Struct. Chem., 56, No. 1, 113–120 (2015).
A. S. Burlov, S. A. Nikolaevskii, A. S. Bogomyakov, et al., Russ. J. Coord. Chem., 35, No. 7, 486–491 (2009).
A. S. Burlov, V. N. Ikorskii, S. A. Nikolaevskii, et al., Russ. J. Inorg. Chem., 53, No. 10, 1566–1572 (2008).
Y. Nishida, M. Masumoto, and Y. Mori, Z. Naturforch. B, 44, No. 10, 307–311 (1989).
Y.-C. Chou, S.-F. Huang, R. Koner, et al., Inorg. Chem., 43, No. 9, 2759–2761 (2004).
T.-C. Lai, W.-H. Chen, C.-J. Lee, et al., J. Mol. Struct., 935, 97–101 (2009).
CrysAlisPro. Version 1.171.36.32.Agilent Technologies (release 02-08-2013).
G. M. Sheldrick, Program for the Refinement of Crystal Structure, Univ. of Göttingen, Göttingen, Germany (1997).
T. Kawata, S. Ohba, Y. Nishida, and T. Tokii, Acta Crystallogr. C 49, No. 12, 2070–2072 (1993).
O. Kahn, Molecular Magnetism, VCH Publishers, New York (1993).
I. N. Shcherbakov, S. I. Levchenkov, Yu. P. Tupolova, et al., Eur. J. Inorg. Chem. 2013, No. 28, 5033–5043 (2013).
S. I. Levchenkov, I. N. Shcherbakov, L. D. Popov, et al., Russ. J. Coord. Chem., 40, No. 8, 523–530 (2014).
L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, et al., Inorg. Chem. Commun., 17, 1–4 (2012).
I. N. Shcherbakov, S. I. Levchenkov, L. D. Popov, et al., Russ. J. Coord. Chem., 41, No. 2, 69–75 (2015).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2017 L. D. Popov, I. N. Shcherbakov, V. G. Vlasenko, S. I. Levchenkov, V. V. Lukov, G. G. Aleksandrov.
†Deceased.
Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 8, pp. 1735-1738, November-December, 2017.
Rights and permissions
About this article
Cite this article
Popov, L.D., Shcherbakov, I.N., Vlasenko, V.G. et al. Crystal structure and magnetic properties of a new polymer dinuclear copper(II) chelate with a schiff base based on 3-formylpyrone and 1,3-diaminopropanol-2. J Struct Chem 58, 1685–1688 (2017). https://doi.org/10.1134/S0022476617080303
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476617080303