Skip to main content
SpringerLink
Log in

Structure and thermal properties of heterometallic complexes for chemical vapor deposition of Cu–Pd films

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Novel volatile heterocomplex compounds based on copper(II) and palladium(II) fluorinated β-diketonates are studied. The crystals of the synthesized compounds are shown to be composed of 1D coordination polymers in the form of chains of alternating molecules of monometallic complexes. The crystallographic data for [Cu(hfa)2∙Pd(zif)2] are as follows: C26H22F18O10CuPd, P21/c, a = 7.9947(18) Å, b = 19.277(4) Å, c = 13.609(3) Å, β = 118.298(15)°, V = 1846.7(7) Å3, Z = 2, d = 1.810 g/cm3. The thermal properties of the compounds are examined by TG-DTA and vacuum sublimation. The complexes are studied as the precursors for producing copper-palladium alloy films by chemical vapor deposition. It is demonstrated that bimetallic alloy coatings with a ratio Cu/Pd = 1:1 can be prepared from [Cu(hfa)2∙Pd(zif)2].

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Veith, J. Chem. Soc. Dalton Trans., 2405–2412 (2002).

    Google Scholar 

  2. L. G. Hubert-Pfalzgraff, Inorg. Chem. Commun. 6, 102–120 (2003).

    Article  Google Scholar 

  3. A. N. Gleizes, Chem. Vap. Deposition 6, 155–173 (2000).

    Article  CAS  Google Scholar 

  4. V. Krisyuk, I. Baidina, A. Turgambaeva, V. Nadolinny, S. Kozlova, I. Korolkov, T. Duguet, C. Vahlas, and I. Igumenov, ChemPlusChem 80, 1457–1464 (2015).

    Article  CAS  Google Scholar 

  5. V. V. Krisyuk, Y. V. Shubin, F. Senocq, A. E. Turgambaeva, T. Duguet, I. K. Igumenov, and C. Vahlas, J. Cryst. Growth., 414, 130–134 (2015).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. V. Krisyuk, S. Urkasym kyzy, I. A. Baidina, I. V. Korolkov, T. P. Koretskaya, N. I. Petrova & A. E. Turgambaeva

  2. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    G. V. Romanenko

Authors
  1. V. V. Krisyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Urkasym kyzy
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. V. Romanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. V. Korolkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. T. P. Koretskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. N. I. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. E. Turgambaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Krisyuk.

Additional information

Original Russian Text © 2017 V. V. Krisyuk, S. Urkasym kyzy, I. A. Baidina, G. V. Romanenko, I. V. Korolkov, T. P. Koretskaya, N. I. Petrova, A. E. Turgambaeva.

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 8, pp. 1573-1580, November-December, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krisyuk, V.V., Urkasym kyzy, S., Baidina, I.A. et al. Structure and thermal properties of heterometallic complexes for chemical vapor deposition of Cu–Pd films. J Struct Chem 58, 1522–1529 (2017). https://doi.org/10.1134/S0022476617080078

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476617080078

Keywords

Search

Navigation