Abstract
The reaction of LnCl3 with Na3salmp/H3salmp (H3salmp = 2-bis(salicylidieneamino)methyl-phenol) affords [LnNa(salmp)(sal)]2 (Ln = Sm(I), Er(II); sal = salicylaldehydato) complexes being different from the known Ln-salmp complex of [Sm(salmp)(THF)]2. In the reaction, the cleavage of C=N bonds happens in H3salmp, and the regenerated salicylaldehydato anion arises and takes part in the coordination. Both complexes are characterized by elemental analysis, IR spectroscopy, and X-ray crystallography.
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References
X. Yang, R. A. Jones, and S. Huang, Coord. Chem. Rev., 273, 63–75 (2014).
J. C. G. Büunzli, Chem. Rev., 110, 2729–2755 (2010).
W. Radecka-Paryzek, V. Patroniak, and J. Lisowski, Coord. Chem. Rev., 249, 2156–2175 (2005).
N. A. R. Nabulsi, F. R. Fronczek, and R. D. Gandour, Acta Crystallogr., C44, 1086–1089 (1988).
B. S. Snyder, G. S. Patterson, A. J. Abrahamson, et al., J. Am. Chem. Soc., 111, No. 14, 5214–5223 (1989).
C. Achim, E. L. Bominaar, R. J. Staples, et al., Inorg. Chem., 40, No. 17, 4389–4403 (2001).
S. B. Yu, C. P. Wang, E. P. Day, et al., Inorg. Chem., 30, No. 21, 4067–4074 (1991).
M. L. Illingsworth, L. J. Schwartz, A. J. Jensen, et al., Polyhedron, 21, No. 2, 211–218 (2002).
P. Chaudhuri, M. Hess, T. Weyhermuller, et al., Inorg. Chem. Commun., 1, No. 2, 39–42 (1998).
E. Bill, C. Krebs, M. Winter, et al., Chem. Eur. J., 3, No. 2, 193–201 (1997).
L. Li, Y. Zhou, and F. G. Yuan, Acta Crystallogr., E68, m603–m604 (2012).
M. M. Zhang, Y. Zhou, F. G. Yuan, et al., Chin. J. Struct. Chem., 33, No. 2, 258–262 (2014).
Rigaku, CrystalClear. Rigaku Corporation., Tokyo, Japan (2004).
G. M. Sheldrick, Acta Crystallogr., A64, 112–122 (2008).
R. D. Shannon, Acta Crystallogr., A32, 751–767 (1976).
Y. Zhong, J. Yang, and L. Hu, Acta Crystallogr., E69, m430 (2013).
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Original Russian Text © 2017 L. Li, F. Yuan.
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Li, L., Yuan, F. Unexpected C=N bond cleavage in H3salmp: Synthesis and structures of [LnNa(salmp)(sal)]2·6EtOH (Ln = Sm, Er; H3salmp = 2-bis(salicylidieneamino) methylphenol; sal = salicylaldehydato). J Struct Chem 58, 1472–1476 (2017). https://doi.org/10.1134/S0022476617070319
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DOI: https://doi.org/10.1134/S0022476617070319