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Structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one

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Abstract

The structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one is studied by the XRD. It is determined that the compound is built as a spacer-armed dinuclear complex in which coordination polyhedra are linked by three aliphatic bridges packed in the asymmetric triple helix. The coordination polyhedron of the gadolinium cation has a slightly distorted three-capped trigonal prism geometry.

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Authors and Affiliations

  1. Vernadsky Crimean Federal University, Simferopol, Russia

    V. F. Shul′gin, O. V. Konnik & Z. Z. Bekirova

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    G. G. Aleksandrov, M. A. Kiskin & I. L. Eremenko

Authors
  1. V. F. Shul′gin
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  2. O. V. Konnik
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  3. Z. Z. Bekirova
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  4. G. G. Aleksandrov
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  5. M. A. Kiskin
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  6. I. L. Eremenko
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Corresponding author

Correspondence to V. F. Shul′gin.

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Original Russian Text © 2017 V. F. Shul′gin, O. V. Konnik, Z. Z. Bekirova, G. G. Aleksandrov, M. A. Kiskin, I. L. Eremenko.

† Deceased.

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Shul′gin, V.F., Konnik, O.V., Bekirova, Z.Z. et al. Structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one. J Struct Chem 58, 1464–1467 (2017). https://doi.org/10.1134/S0022476617070290

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  • DOI: https://doi.org/10.1134/S0022476617070290

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