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A novel dinuclear CuII complex based on flexible bis(triazole): Synthesis, structure and physical properties

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Abstract

New dinuclear copper(II) complex [Cu2(BTE)2(N3)4] (1) (BTE = 1,1′-(2,2′-oxybis(ethane-2,1-diyl))bis(1H-1,2,4-triazole)) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that complex 1 is a centrosymmetric dinuclear Cu(II) cluster unit with a Cu–Cu separation of 3.267(6) Å. In addition, complex 1 exhibits a high photocatalytic degradation activity for the degradation of rhodamine B.

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Authors and Affiliations

  1. School of Chemistry & Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu, P.R. China

    X.-J. Xu, X. Fang, H.-N. Yu, Z. Zhou & J. Wang

Authors
  1. X.-J. Xu
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  2. X. Fang
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  3. H.-N. Yu
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  4. Z. Zhou
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  5. J. Wang
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Correspondence to X.-J. Xu.

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Original Russian Text © 2017 X.-J. Xu, X. Fang, H.-N. Yu, Z. Zhou, J. Wang.

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Xu, XJ., Fang, X., Yu, HN. et al. A novel dinuclear CuII complex based on flexible bis(triazole): Synthesis, structure and physical properties. J Struct Chem 58, 1440–1442 (2017). https://doi.org/10.1134/S0022476617070241

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  • DOI: https://doi.org/10.1134/S0022476617070241

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