Abstract
A new dinuclear nitrido-bridged ruthenium complex with pyridine ligands ([PyH][Ru2N(Py)4Cl6] (1) is synthesized by reacting K3[Ru2NCl8(H2O)2] (2) and excessive pyridine, then crystallized from dilute hydrochloric acid. Its crystal structure is determined by single crystal X-ray diffraction. The complex crystallizes in the form of red block crystals of the monoclinic symmetry and the space group C 2. The nitrido-bridged ruthenium complex has very short Ru–N distances.
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The text was submitted by the authors in English.
Zhurnal Strukturnoi Khimii, Vol. 58, No. 3, pp. 650-651, March-April, 2017.
Original Russian Text © 2017 Q. W. Chang, C. X. Yan, J. Jiang, Q. S. Ye, J. Yu, J. L. Chen, H. Cui, W. P. Liu.
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Chang, Q.W., Yan, C.X., Jiang, J. et al. Crystal structure of a dinuclear nitrido-bridged ruthenium complex with pyridine ligands. J Struct Chem 58, 624–626 (2017). https://doi.org/10.1134/S0022476617030295
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DOI: https://doi.org/10.1134/S0022476617030295