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Crystal structure of 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undec-1-ylmethyl-2-methylacrylate

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Abstract

The XRD method is used to determine the molecular and crystal structure of 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undec-1-ylmethyl-2-methylacrylate (H2C=C(Me)C(O)OCH2Si(OCH2CH2)3N). The crystallographic data are as follows: space group Р212121, а = 9.7659(1) Å, b = 10.017(1) Å, с = 17.915(2) Å, V = 1753.3(3) Å3, Z = 4. The coordination polyhedron of the silicon atom is a distorted trigonal bipyramid. The length of the N→Si coordination bond is 2.099 Å.

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References

  1. CS Patent 128408 (1968).

  2. DE Patent 2113217 (1971).

  3. N. E. Gelman, E. A. Terentieva, T. M. Shanina, L. M. Kiparenko, and V. Rezl, Methods of Quantitative Organic Elemental Microanalysis [in Russian], Khimiya, Moscow (1987).

    Google Scholar 

  4. G. M. Sheldrick, Acta Crystallogr., А64, No. 1, 112–122 (2008).

    Article  Google Scholar 

  5. APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11), Bruker Advanced X-ray Solutions, Madison, Wisconsin, USA (2004).

  6. V. Pestunovich, S. Kirpichenko, and M. Voronkov, in: The Chemistry of Organic Silicon Compounds, vol. 2, Z. Rappoport and Y. Apeloig (eds.), Wiley & Sons, N.Y. (1998), pp. 1447–1537.

    Book  Google Scholar 

  7. M. G. Voronkov, E. A. Zelbst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 376, No. 2, 204–206 (2001).

    CAS  Google Scholar 

  8. M. G. Voronkov, E. A. Zelbst, V. S. Fundamensky, et al., Dokl. Akad. Nauk, 381, No. 3, 348–350 (2001).

    CAS  Google Scholar 

  9. M. G. Voronkov, E. A. Zelbst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 386, No. 1, 56–60 (2002).

    Google Scholar 

  10. M. G. Voronkov, E. A. Zelbst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 389, No. 4, 478–481 (2003).

    Google Scholar 

  11. M. G. Voronkov, V. S. Fundamensky, E. A. Zelbst, et al., Dokl. Akad. Nauk, 401, No. 1, 41–43 (2005).

    Google Scholar 

  12. M. G. Voronkov, E. A. Zelbst, V. S. Fundamensky, et al., J. Struct. Chem., 46, No. 6, 1122–1125 (2005).

    Article  CAS  Google Scholar 

  13. Cambridge Structural Data base System. Version 1.17.2014.

  14. F. H. Allen, D. G. Watson, L. Brammer, et al., Int. Tables Crystallogr., vol. C (2006), pp. 790–811.

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    Yu. I. Bolgova, T. N. Borodina, O. M. Trofimova & V. I. Smirnov

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  1. Yu. I. Bolgova
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  2. T. N. Borodina
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  3. O. M. Trofimova
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  4. V. I. Smirnov
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Corresponding author

Correspondence to O. M. Trofimova.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 3, pp. 638-640, March-April, 2017.

Original Russian Text © 2017 Yu. I. Bolgova, T. N. Borodina, O. M. Trofimova, V. I. Smirnov.

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Bolgova, Y.I., Borodina, T.N., Trofimova, O.M. et al. Crystal structure of 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undec-1-ylmethyl-2-methylacrylate. J Struct Chem 58, 611–614 (2017). https://doi.org/10.1134/S002247661703026X

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  • DOI: https://doi.org/10.1134/S002247661703026X

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