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Crystal structure and physical properties of a one-dimensional coordination polymer based on 2,2′-bis(1H-1,2,4-triazolyl)ether

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Abstract

A one-dimensional Cu(II) complex [Cu(BTE)2(ClO4)2] n (1) (BTE = 2,2′-bis(1H-1,2,4-triazolyl)ether) is synthesized and characterized using single crystal X-ray diffraction, IR, and elemental analysis. Single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional chain based on the rhomboid subunit [Cu2(BTE)2] with a Cu…Cu separation of 9.0912(2) Å. There is no magnetic coupling between the CuII ions. Complex 1 displays a high photocatalytic degradation activity for methylene blue.

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Authors and Affiliations

  1. School of Chemistry & Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu, P. R. China

    X. X. Juan, Z. Zhou, L. Li & J.-Q. Tao

Authors
  1. X. X. Juan
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  2. Z. Zhou
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  3. L. Li
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  4. J.-Q. Tao
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Corresponding author

Correspondence to X. X. Juan.

Additional information

The text was submitted by the authors in English.

Zhurnal Strukturnoi Khimii, Vol. 58, No. 3, pp. 631-634, March-April, 2017.

Original Russian Text © 2017 X. X. Juan, Z. Zhou, L. Li, J.-Q. Tao.

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Juan, X.X., Zhou, Z., Li, L. et al. Crystal structure and physical properties of a one-dimensional coordination polymer based on 2,2′-bis(1H-1,2,4-triazolyl)ether. J Struct Chem 58, 603–607 (2017). https://doi.org/10.1134/S0022476617030246

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  • DOI: https://doi.org/10.1134/S0022476617030246

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