Abstract
The single crystal X-ray diffraction study of the heterometallic cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6 is performed. The crystallographic characteristics are as follows: a = 32.356(15) Å, b = 11.754(5) Å, c = 20.114(9) Å, β = 115.707(6)°, V = 6893(5) Å3, space group C2/c, Z = 8, d calc = 1.741 g/cm3. The cluster molecule contains a bridging phenylvinylidene ligand coordinated to a metallic core in the form of a Mn–Fe–Pt chain (the Mn–Fe and Fe–Pt bond lengths are 2.6768(14) Å and 2.6280(11) Å respectively and the Mn⋯Pt distance is 3.6425(19) Å).
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Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 3, pp. 628-630, March- April, 2017.
Original Russian Text © 2017 O. S. Chudin, V. V. Verpekin, A. D. Vasiliev, A. I. Rubaylo.
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Chudin, O.S., Verpekin, V.V., Vasiliev, A.D. et al. Structure of a trinuclear μ3-vinylidene cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6 . J Struct Chem 58, 600–602 (2017). https://doi.org/10.1134/S0022476617030234
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DOI: https://doi.org/10.1134/S0022476617030234