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Crystal structure of new ammonium fluoroindate(III) (NH4)2[InF5]

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Abstract

A new indium(III) fluoride complex with the ammonium cation (NH4)2[InF5] is synthesized and its crystal structure is studied. The structure of (NH4)2[InF5] is formed of NH4 + cations and complex [InF5]2– anions. The In atom in the complex anion surrounded by four terminal and two bridging F atoms forms an almost regular octahedral coordination polyhedron (CN 6) with two terminal F atoms in the axial positions and two terminal and two bridging F atoms in the equatorial plane. Through bridging F atoms, the InF6 polyhedra are arranged in polymer trans- vertex-connected corrugated anion chains (InF5) n 2n− directed along the c axis. The N–H⋯F hydrogen bonds organize the chains in a three-dimensional framework.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia

    R. L. Davidovich & V. B. Logvinova

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    V. V. Tkachev & G. V. Shilov

Authors
  1. R. L. Davidovich
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  2. V. B. Logvinova
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  3. V. V. Tkachev
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  4. G. V. Shilov
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Correspondence to R. L. Davidovich.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 3, pp. 614-616, March-April, 2017.

Original Russian Text © 2017 R. L. Davidovich, V. B. Logvinova, V. V. Tkachev, G. V. Shilov.

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Davidovich, R.L., Logvinova, V.B., Tkachev, V.V. et al. Crystal structure of new ammonium fluoroindate(III) (NH4)2[InF5]. J Struct Chem 58, 585–587 (2017). https://doi.org/10.1134/S0022476617030192

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  • DOI: https://doi.org/10.1134/S0022476617030192

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