Journal of Structural Chemistry

, Volume 58, Issue 2, pp 366–369 | Cite as

Molecular and crystal structure of a novel Schiff base: 4-methyl-N-[2-[(2-methyl-4-oxo-quinazoline-3-yl)iminomethyl]phenyl]benzenesulfonamide

  • L. D. Popov
  • S. A. Borodkin
  • Yu. P. Tupolova
  • S. I. Levchenkov
  • V. V. Tkachev
  • A. S. Burlov
  • A. A. Tsaturyan
Brief Communications
  • 42 Downloads

Abstract

A novel Schiff base is synthesized by condensation of 4-methylphenylsulfonyl-2-benzaldehyde and N-aminoquinazoline-4-one. The molecular and crystal structure of the produced compound is determined by the XRD method. It is found that the crystal contains two independent molecules between which a π-stacking interaction occurs.

Keywords

Schiff base single crystal X-ray diffraction analysis NMR crystal structure molecular structure 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    S. Kumar, G. Mishra, P. Singh, et al., Chem. Sin., 2, No. 4, 36 (2011).Google Scholar
  2. 2.
    A. K. Nanda, S. Ganduli, and R. Chakraborty, Molecules, 12, No. 10, 2413 (2007).CrossRefGoogle Scholar
  3. 3.
    P. Panneerselvam, B. R. Ahmad, R. D. Sankar, and R. N. Kumar, Eur. J. Med. Chem., 44, No. 5, 2328 (2009).CrossRefGoogle Scholar
  4. 4.
    K. B. Gudasi, R. S. Vadavi, R. V. Shenoy, et al., Transition Met. Chem., 30, No. 6, 661 (2005).CrossRefGoogle Scholar
  5. 5.
    M. D. Mashkovsky, Medical Compounds, Novaya Volna, Moscow (2012).Google Scholar
  6. 6.
    L. D. Popov, Yu. P. Tupolova, V. V. Lukov, et al., Inorg. Chim. Acta, 362, No. 6, 1673 (2009).CrossRefGoogle Scholar
  7. 7.
    L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, et al., Russ. J. Coord. Chem., 39, No. 4, 233 (2013).CrossRefGoogle Scholar
  8. 8.
    M. R. Bermejo, M. Vazques, J. Sanmartin, et al., New J. Chem., 26, No. 10, 1365 (2002).CrossRefGoogle Scholar
  9. 9.
    A. S. Burlov, S. A. Mashchenko, O. A. Ivashchenko, et al., Russ. J. Gen. Chem., 79, No. 3, 412 (2009).CrossRefGoogle Scholar
  10. 10.
    A. S. Burlov, V. G. Vlasenko, Yu. V. Koshchienko, et al., Russ. J. Coord. Chem., 42, No. 4, 237 (2016).CrossRefGoogle Scholar
  11. 11.
    A. S. Burlov, V. G. Vlasenko, N. I. Makarova, et al., Polyhedron, 107, No. 3, 153 (2016).CrossRefGoogle Scholar
  12. 12.
    A. S. Burlov, V. G. Vlasenko, Yu. V. Koshchienko, D. A. Garnovskii, A. I. Uraev, A. V. Metelitsa, A. S. Cheprasov, and V. I. Minkin, RF Patent 2562456, Bul. No. 25 (10.09.2015).Google Scholar
  13. 13.
    A. S. Burlov, E. I. Maltsev, V. G. Vlasenko, et al., Russ. Chem. Bull., 63, No. 8, 1759 (2014).CrossRefGoogle Scholar
  14. 14.
    A. S. Burlov, Yu. V. Koshchienko, V. G. Vlasenko, et al., Russ. J. Coord. Chem., 40, No. 8, 460 (2014).CrossRefGoogle Scholar
  15. 15.
    A. S. Burlov, Yu. V. Koshchienko, M. A. Kiskin, et al., J. Mol. Struct., 1104, 7 (2016).CrossRefGoogle Scholar
  16. 16.
    G. M. Sheldrick, SHELXTL v. 6.14, Structure Determination Software Suite, Bruker AXS, Madison, USA, Wisconsin (2000).Google Scholar
  17. 17.
    G. L. Perlovich, A. M. Ryzhakov, V. V. Tkachev, et al., Cryst. Growth Des., 13, No. 9, 4002 (2013).CrossRefGoogle Scholar
  18. 18.
    K. S. Eccles, S. P. Stokes, C. A. Daly, et al., J. Appl. Crystallogr., 44, 213 (2011).CrossRefGoogle Scholar
  19. 19.
    B. T. Gowda, S. Foro, P. G. Nirmala, et al., Acta Crystallogr., Sect. E, 65, o1219 (2009).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • L. D. Popov
    • 1
  • S. A. Borodkin
    • 1
  • Yu. P. Tupolova
    • 1
  • S. I. Levchenkov
    • 1
    • 2
  • V. V. Tkachev
    • 3
  • A. S. Burlov
    • 4
  • A. A. Tsaturyan
    • 4
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  3. 3.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussia
  4. 4.Research Scientific Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia

Personalised recommendations