Journal of Structural Chemistry

, Volume 58, Issue 2, pp 358–361 | Cite as

Crystal structure of copper(II) 2-methyl-3-{[3-methyl-5-oxo-1-phenylpyrazole-4-ylidene-methyl]amino}-quinazoline-4-onate

  • L. D. Popov
  • S. A. Borodkin
  • V. V. Tkachev
  • Yu. P. Tupolova
  • A. S. Burlov
  • G. V. Shilov
  • A. N. Utenyshev
Brief Communications
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Abstract

The crystal and molecular structure of a copper(II) complex based on 2-methyl-3-{[3-methyl-5-oxo-1-phenylpyrazole-4-ylidene-methyl]amino}-quinazoline-4-one is studied by single crystal X-ray diffraction. The chelate core is demonstrated to have a pyramidal structure.

Keywords

single crystal X-ray diffraction (XRD) copper(II) complex crystal structure 

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References

  1. 1.
    M. D. Mashkovsky, The Medical Drugs, Novaya Volna, Moscow (2012).Google Scholar
  2. 2.
    M. Cushman, M. Jayaraman, J. A. Vroman, et al., J. Med. Chem., 43, 3665 (2000).CrossRefGoogle Scholar
  3. 3.
    Z.-G. Yu, W.-M. Ding, H.-R. Ji, and X.-Y. Zhu, Chin. J. Org. Chem., 30, No. 9, 1358 (2010).Google Scholar
  4. 4.
    B. A. Omotowa and M. A. Mesubi, Appl. Organomet. Chem., 11, No. 1, 1 (1997).CrossRefGoogle Scholar
  5. 5.
    S. I. Levchenkov, I. N. Shcherbakov, L. D. Popov, et al., J. Struct. Chem., 56, No. 1, 113 (2015).CrossRefGoogle Scholar
  6. 6.
    L. D. Popov, S. A. Borodkin, I. N. Shcherbakov, et al., Russ. J. Gen. Chem., 83, No. 7, 1376 (2013).CrossRefGoogle Scholar
  7. 7.
    S. Kumar, G. Mishra, P. Singh, et al., Chem. Sin., 2, No. 4, 36 (2011).Google Scholar
  8. 8.
    A. K. Nanda, S. Ganduli, and R. Chakraborty, Molecules, 12, No. 10, 2413 (2007).CrossRefGoogle Scholar
  9. 9.
    P. Panneerselvam, B. R. Ahmad, R. D. Sankar, and R. N. Kumar, Eur. J. Med. Chem., 44, No. 5, 2328 (2009).CrossRefGoogle Scholar
  10. 10.
    K. B. Gudasi, R. S. Vadavi, R. V. Stenoy, et al., Transition Met. Chem., 30, No. 6, 661 (2005).CrossRefGoogle Scholar
  11. 11.
    P. K. Shiva, K. L. Shiva, P. Melvin, et al., Biointerface Res. Appl. Chem. Open Access J., 1, No. 4, 127 (2011).Google Scholar
  12. 12.
    K. S. Prasad, L. S. Kumar, S. Chandan, et al., Spectrochim. Acta., Part A, 81, 276 (2011).Google Scholar
  13. 13.
    K. B. Gudasi, R. S. Vadavi, R. V. Stenoy, et al., Transition Met. Chem., 31, No. 1, 135 (2006).CrossRefGoogle Scholar
  14. 14.
    L. D. Popov, S. A. Borodkin, Yu. P. Tupolova, et al., Russ. J. Gen. Chem., 85, No. 7, 1706 (2015).CrossRefGoogle Scholar
  15. 15.
    G. M. Sheldrick, SHELXTL v. 6.14, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA (2000).Google Scholar
  16. 16.
    N. Shinozaki, S. Motomizu, K. Toei, et al., Rep. Res. Lab. Surf. Sci., Okayama Univ., 4, 199 (1976).Google Scholar
  17. 17.
    J. Korvenranta and H. Saarinen, Acta Chem. Scand., 29A, 861 (1975).CrossRefGoogle Scholar
  18. 18.
    K. Malek, M. Vala, J. Swiatek-Kozlowska, and L. M. Proniewicz, New J. Chem., 28, 477 (2004).CrossRefGoogle Scholar
  19. 19.
    Yu. A. Simonov, T. Yu. Sliva, M. D. Mazus, et al., Russ. J. Inorg. Chem., 34, No. 4, 873 (1989).Google Scholar
  20. 20.
    C. B. Castellani, O. Carugo, and A. Coda, Acta Crystallogr,. Sect. C, 44, 267 (1988).CrossRefGoogle Scholar
  21. 21.
    V. V. Ponomareva, N. K. Dalley, X. Kou, et al., J. Chem. Soc., Dalton Trans., 2351 (1996).Google Scholar
  22. 22.
    I. O. Fritsky, H. Kozlowski, E. V. Prisyazhnaya, et al., J. Chem. Soc., Dalton Trans., 1535 (1998).Google Scholar
  23. 23.
    A. Krzan, P. Kamaras, M. H. Dickman, et al., Acta Chim. Slov., 48, 229 (2001).Google Scholar
  24. 24.
    V. K. Belsky, R. V. Linko, V. A. Soldatkina, et al., Russ. J. Inorg. Chem., 46, No. 2, 246 (2001).Google Scholar
  25. 25.
    M. Hamelin, Acta Crystallogr., Sect. B., 28, 228 (1972).CrossRefGoogle Scholar
  26. 26.
    M. A. R. Molina, J. D. M. Ramos, D. L. Gonzalez, and C. V. Calahorro, An. Quim. Ser. B, 79, 200 (1983).Google Scholar
  27. 27.
    V. V. Lukov, G. G. Aleksandrov, E. V. Dontsova, et al., Russ. J. Coord. Chem., 31, No. 10, 732 (2005).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • L. D. Popov
    • 1
  • S. A. Borodkin
    • 1
  • V. V. Tkachev
    • 2
  • Yu. P. Tupolova
    • 1
  • A. S. Burlov
    • 3
  • G. V. Shilov
    • 2
  • A. N. Utenyshev
    • 2
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussia
  3. 3.Research Scientific Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia

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