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Molecular and crystal structure of a cationic dinitrosyl iron complex with 1,3-dimethylthiourea

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Abstract

A new dinitrosyl iron complex of the composition [Fe(SC(NHCH3)2)2(NO)2]Cl (I) is obtained by direct nitrosylation of ferrous sulfate and a hydrochloric acid solution of 1,3-dimethylthiourea. The characteristic features of the molecular and crystal structure of complex I is determined by single crystal X-ray diffraction analysis.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    N. Yu. Shmatko, D. V. Korchagin, G. V. Shilov, N. A. Sanina & S. M. Aldoshin

Authors
  1. N. Yu. Shmatko
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  2. D. V. Korchagin
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  3. G. V. Shilov
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  4. N. A. Sanina
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  5. S. M. Aldoshin
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Corresponding author

Correspondence to N. Yu. Shmatko.

Additional information

Original Russian Text © 2017 N. Yu. Shmatko, D. V. Korchagin, G. V. Shilov, N. A. Sanina, S. M. Aldoshin.

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 2, pp. 370–372, February–March, 2017.

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Shmatko, N.Y., Korchagin, D.V., Shilov, G.V. et al. Molecular and crystal structure of a cationic dinitrosyl iron complex with 1,3-dimethylthiourea. J Struct Chem 58, 353–355 (2017). https://doi.org/10.1134/S0022476617020172

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  • DOI: https://doi.org/10.1134/S0022476617020172

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