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Xanes of X-ray absorbtion K edges of chromium dichalcogenides CuCr1-x M′ x S2 and MCrX2

  • Applications of Synchrotron Radiation in Structural Chemistry
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Abstract

In the work X-ray K edges of chromium dichalcogenides CuCr1-x M ′ x S2 (M = V, Fe; x = 0-0.40) and MCrX2 (M = Cu, Ag, Na; X = O, S, Se) were studied experimentally and theoretically. Comparison of fine structures of experimental XANES spectra obtained using a synchrotron radiation source and theoretical absorption spectra modelled using FDMNES software package allows one to study the influence of types of intercalate M, chalcogene X and also the effect of the cation substitution of chromium atoms by vanadium and iron on XANES structure of K edges in CuCr1-x M ′ x S2 and MCrX2.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. V. Korotaev, N. N. Peregudova, M. M. Syrokvashin, L. N. Mazalov, V. V. Sokolov, I. Yu. Filatova & A. Yu. Pichugin

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    V. V. Kanazhevskiy & L. N. Mazalov

  3. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. V. Kanazhevskiy

Authors
  1. E. V. Korotaev
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  2. V. V. Kanazhevskiy
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  3. N. N. Peregudova
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  4. M. M. Syrokvashin
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  5. L. N. Mazalov
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  6. V. V. Sokolov
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  7. I. Yu. Filatova
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  8. A. Yu. Pichugin
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Corresponding author

Correspondence to E. V. Korotaev.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 7, pp. 1430-1437, September-October, 2016.

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Korotaev, E.V., Kanazhevskiy, V.V., Peregudova, N.N. et al. Xanes of X-ray absorbtion K edges of chromium dichalcogenides CuCr1-x M′ x S2 and MCrX2 . J Struct Chem 57, 1355–1361 (2016). https://doi.org/10.1134/S0022476616070088

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  • DOI: https://doi.org/10.1134/S0022476616070088

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