Abstract
The structure of two crystalline modifications of [Pb3(OH)4Co(NO2)3](NO2)2 containing tetrahedral [Pb3(OH)4Co(NO2)3]2+ complex cations is studied. Three lead atoms and one cobalt atom are located in the vertices of a distorted tetrahedron with the edges of 3.39-3.92 Å. The distances from the metal atoms to the oxygen atoms belonging to μ3 bridging hydroxo groups are within 1.910-1.956 Å for Co–O and 2.340-2.439 Å for Pb–O. The packing motifs of the crystal structures are analyzed.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 5, pp. 1095-1099, June-July, 2016.
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Khranenko, S.P., Kuratieva, N.V. & Gromilov, S.A. A family of crystal structures with [Pb3(OH)4Co(NO2)3]2+ cations. J Struct Chem 57, 1044–1048 (2016). https://doi.org/10.1134/S0022476616050292
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DOI: https://doi.org/10.1134/S0022476616050292